(CYCLOHEXENYLOXY)TRIMETHYLSILANE

Product Code: SIC2462.0
CAS No: 6651-36-1
SDS Sheets: EU | US
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6651-36-1
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2 kg
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    229-675-1
  • Synonyms

    1-(TRIMETHYLSILOXY)CYCLOHEXENE
  • HMIS

    3-2-1-X
  • Molecular Formula

    C9H18OSi
  • Molecular Weight (g/mol)

    170.33
  • Purity (%)

    97%
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    67-68/16
  • Density (g/mL)

    0.885
  • Flash Point (˚C)

    51 °C
  • Refractive Index @ 20˚C

    1.447

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Reacts with ethylene oxide to give ?-hydroxy ketones.1
    Reacts with aldehydes, acetals, and enones w/o Lewis acid catalysis in the presence of hexafluoro-2-propanol.2
    Hydroboration/oxidation leads to trans-1,2-diols.3
    Hydroboration/elimination converts silyl enol ethers to olefins.4

    Reference

    1. Lalic, G. et al. Tetrahedron Lett. 2000, 41, 763.
    2. Ratnikov, M. O. et al. Angew. Chem., Int. Ed. Engl.2008, 47, 9739.
    3. Larson, G. L. et al. J. Organomet. Chem. 1974, 76, 9.
    4. Larson, G. L. et al. Tetrahedron Lett. 1975, 4005.

    Safety

  • Packaging Under

    Nitrogen