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Staff Publications (partial list)
Barry C. Arkles - Publications
114. Arkles, B., Pan, Y. Kim. Y.M, The Role of Polarity on the Substitution of Silanes Employed in Surface Modification, in “Silanes and Other Coupling Agents Vol 5, K. Mittal Ed. p.51 VSP (Brill) 2009
113. Arkles, B., Zazyczny, J, Dipodal Silanes, Adhesives and Sealants Industry, Nov. 2008
112. Kaloyeros, A., Stan, M.R., Arkles, B., Geer, R., Eisenbraun, E. T., Reynolds, J.E., Gadre, A., Yongqiang Xue, Ryan, J., Conformational Molecular Switches for Post-CMOS Nanoelectronics, IEEE Transactions: Circuits and Systems 1, 54(11), 2345-2352, Nov. 2007
111. Arkles, B., Hydrophobicity, Hydrophilicity and Silanes, Paint and Coatings International, 22(10), 114, 2006.
110. Arkles, B., Pan, Y Larson, J, Berry, D., Cyclic Azasilanes: Volatile Coupling Agents for Nanotechnology, in Silanes and Other Coupling Agents, Vol. 3, K. Mittal (Ed.) VSP (Brill), 2004, p 179-191
109. Arkles, B. Commercial Applications of Sol-Gel-Derived Hybrid Materials, MRS Bulletin, 26(5), 402, 2001
108. Ezbiansky, K., Berry, D., Composto, R., Arkles, B. Fluoride Catalyzed Conversion of b-acetoxethylsilsesquioxane: chloride free precursor for silica films, Polymer Preprints, 42(12), 2001
107. Londergan, A., Nuesca, G., Goldberg, C., Peterson, G. Kaloyeros, A., Arkles, B., Sullivan, J., Interlayer Mediated Epitaxy of Cobalt Silicide on Silicon (100) from Low Temperature Chemical Vapor Deposition of Cobalt: Formation Mechanisms and Associated Properties J. Electrochem. Soc., 148, C21, 2001
106. Kaloyeros, A., Chen, X., Lane, S., Frisch, H., Arkles, B., Tantalum diffusion barrier grown by inorganic plasma-promoted chemical vapor deposition: Performance in copper metallization, J. Mater. Res., 15(12), 2000.
105. Laxman, R., Hendricks, N., Arkles, B., Tabler, T., Synthesizing Low-k Materials for Fab Use, Semiconductor International, Nov., 2000
104. Eisenbraun, E., Upham, A., Dash, R., Zeng, W., Hoefnagels, J., Lane, S., Anjum, D., Dovidenko, K., Kaloyeros, A., Arkles, B., Sullivan, J., Low temperature inorganic chemical vapor deposition of Ti-Si-N diffusion barriers for gigascale copper interconnect applications, J. Vac. Sci. Technol. B 18(4), 2011, 2000
103. Ezbiansky, K., Arkles, B., Composto, R., Berry, D., b-Acetoxyethyl Silsesquioxanes: Chloride-Free Precursors for SiO2 Films via Staged Hydrolysis, MRS Proc., 606, 251, 2000
102. Arkles, B., Commercial Hybrid Organic-Inorganic Polymers in “Organosilicon Chemistry IV” eds. Auner, N, Weiss, J., p.592-612, Wiley-VCH, 2000.
101. Eisenbraun, E., Kelsey, J., Lane,, S., Belyansky, Y., Carlsen, A., Kumar, K., Anjum, Kaloyeros, A., Arkles, B., Sullivan, J., Integration of CVD W- and Ta-based Liners for Copper Metallization, Semiconductor Online.1/19/2000
100. Arkles, B., Hybrid Polymers in the Marketplace, CHEMTECH, 29(12), 7, 1999.
99. Ivanova, A., Nuesca, G., Chen, X., Goldberg, C., Kaloyeros, A., Arkles, B., Sullivan, J., The Effects of processing parameters in the chemical vapor deposition of cobalt from cobalt tricarbonyl nitrosyl, J. Electrochem. Soc., 146(6), 2139, 1999.
98. Pan, Q., Gonzalez, B., Composto, R., Wallace, W., Arkles, B., Figge, L., Berry, D Spin-on-glass thin films prepared from a novel polysilsesquioxane by thermal and ultraviolet-irradiation methods, Thin Solid Films, 345, 244, 1999
97. Chen, X., Peterson, G., Goldberg, C., Nuesca, G., Frisch, H., Kaloyeros, A., Arkles, B., Sullivan, J., Low-Temperature Chemical Vapor Deposistion of Tantalum Nitride from Tantalum Pentabromide for Integrated Circuity Copper Metallization Applications, J. Mater. Res., 14(5), 2043, 1999
96. Kelsey, J., Goldberg, C., Nuesca, G., Peterson, G., Kaloyeros, A., Arkles, B., Low Temperature Metal-Organic Chemical Vapor Deposition of Tungsten Nitride as Diffusion Barrier for Copper Metallization, J. Vac. Sci. Technol., B 17(3), 1101, 1999.
95. Chen, X., Frisch, H., Kaloyeros, A., Arkles, B., Low Temperature Plasma-Promoted Chemical Vapor Deposition of Tantalum Nitride from Tantalum Bromide for Copper Metallization,
J. Vac. Sci. Technol., B 17(1), 182, 1999.
94. Chen, X., Frisch, H., Kaloyeros, A., Arkles, B., Low Temperature Plasma-Promoted Chemical Vapor Deposition of Tantalum from Tantalum Bromide for Copper Metallization,
J. Vac. Sci. Technol., B 16(5), 2887, 1998
93. Kumta, P., Hepp, A., Beach, D., Arkles, B., Sullivan, J., editors “Chemical Aspects of Electronic Ceramics Processing”, MRS, 1998.
92. Lin, L., Endisch, D., Chen, X., Kaloyeros, A., Arkles, B., Silicon Nitride Films Deposited by Atmospheric Pressure Chemical Vapor Deposition, MRS Proc., 495, 107, 1998.
91. Faltermeier, C., Goldberg, C., Jones, M., Upham, A., Kerr, A., Ivanova, A., Peterson, G., Kaloyeros, A., Arkles, B., The Effects of Processing Parameters in the Low-Temperature Chemical Vapor Deposition of Titanium Nitride from Tetraiodotitanium,” J. Electrochemical Society, 145, 676, 1998.
90. Arkles, B., Silicon Compounds (Ethers and Esters), Kirk-Othmer Encyclopedia of Chemical Technology, 22, 69,1997, Wiley.
89. Arkles, B., Silicon Compounds (Silanes), Kirk-Othmer Encyclopedia of Chemical Technology, 22, 38, 1997, Wiley.
88. Arkles, B., Berry, D., Figge, L., Composto, R. Chiou, T., Colazo, H., Wallace, W., Staged Development of Silicon Dioxide Films, Journal of Sol-Gel Science and Technology, 8, 465, 1997
87. Faltermeier, C., Goldberg, C., Jones, M., Upham, A., Manger, D., Peterson, G., Lau, J., Kaloyeros, A., Arkles, B., Paranjpe, A., Barrier Properties of Titanium Nitride Films Grown by Low Temperature Chemical Vapor Deposition from Titanium Tetraiodide,” J. Electrochemical Society, 144, 1002, 1997.
86. Arkles, B., Grignard Reagents and Silanes in “Handbook of Grignard Reagents” G. Silverman and P. Rakita eds, Marcel-Dekker, p.667, 1996.
85. Goldberg, C., Eisenbraun, E., Komarov, S., Faltermeier, C., Chen, X., Jones, M., Avanova, A., Flordalice, R., Pintchovski, F., Arkles, B., Hepp, A., Kaloyeros, A., Low Temperature In-Situ Chemical Vapor Deposition of Ti/TiN Ultrathin Bilayers for ULSI Barrier Applications in “Advanced Metallization for ULSI Applications 1994” eds. R. Blumenthal, G. Janssen, Mat. Res. Soc. 1995
84. Lou, I., Chen, L., Eisenbraun, E., Shemerhorn, E., Toscano, P., Thomas, M., Arkles, B., Kaloyeros, A., Plasma-Assisted Chemical Vapor Deposition of Gold for ULSI Multilevel Metallization Schemes, in “Advanced Metallization for ULSI Applications 1993” D. Favreau, Y. Sacham-Diamand, Y. Yoriike, Mat. Res. Soc. 1994, p569-573.
83. Arkles, B., Future Directions in Silicon Chemistry, Main Group Chemistry News, 2(2), 4 1994.
82. Faltermeier, F., Eisenbraun, E., Liu, J., Dettelbacher, C., Toscano, P., Arkles., B., Kaloyeros, A., MOCVD of Tungsten for Multilayer Interconnects, in “Advanced Metallization for VLSI Applications 1992” eds. T. Cale, F. Pintchovski, Mat. Res. Soc. 1993
81. Arkles, B., Steinmetz, J., Zazyczny, J., Mehta, P., Factors Contributing to the Stability of Alkoxysilanes in Aqueous Solution, J. Adhesion Sci. & Technol., 6, 193, 1992; also included in “Silanes and Other Coupling Agents” ed. K. Mittal, VSP, 1992, p 91.
80. Arkles, B., Steinmetz, J., Zazyczny, J., Zolotnitsky, M., Stable, Water-Borne Silane Coupling Agents, 46th Soc. Plas. Ind. Composites Inst. Proc., 46, 2-D, 7pp, 1991.
79. Arkles, B., Crosby, J., Polysiloxane - Thermoplastic Interpenetrating Polymer Networks, in ”Silicon Based Polymer Science: A Comprehensive Resource” ed. J. Zeigler, G. Fearon, American Chemical Society, 1990.
78. Arkles, B., Vogelaar, G., Better Way To Pick Silicone Fluid, Machine Design, 60(20), 81, 1988
77. Arkles, B., Steinmetz, J., Hogan, J., Polymeric Silane Coupling Agents Enhance Strength of Composites, Modern Plastics, 64(4), 138, 1987.
76. Pannell, K. H., Rico, E., LaNeave, C., Rahimian, K., Amaya, A., Arkles, B., Silacrown Ionophores, J. Membrane Sci., 32, 83, 1987.
75. Arkles, B., Steinmetz, J., Hogan, J., Polymeric Silanes: An Evolution in Coupling Agents, 42nd Soc. Plastics Ind. Composites Inst. Proc., 42, 21-C, 1987
74. Arkles, B., Lydzinski, D., Brinigar, W., Chao, T., Siliconization: Blood - Surface Interaction in “Silanes, Surfaces and Interfaces” (D. Leyden ed.) Gordon & Breach, New York, 1986.
73. Arkles, B., Silicon Nitride from Organosilazane Cyclic and Linear Prepolymers, J. Electrochem. Soc. 133, 233, 1986.
72. Arkles, B. What are IPN’s?, Plastics Technology, 31(8), 1985.
71. Pannell, K. H., LaNeave, C. K., Rico, E., Arkles, B., Concerning the Relative Non-toxicity of Silacrown Ionophores, Pharm. Biochem. Behav., 21, Supp. 1, 77, 1984.
70. Arkles, B., Carreno, C., Filler-Free Models for the Role of Organofunctional Silanes in Composites. Poly. Mat. Sci, Engg., 50, 440, 1984.
69. Arkles, B., High Performance and Thermoplastic Silicones for Biomedical Applications, Soc. Plas. Eng. 42nd ANTEC Proc., 1080, 1984.
68. Arkles, B., Carreno, C., Silicone IPN Modified Thermoplastics, Soc. Plas. Eng. 42nd ANTEC Proc., 486, 1984.
67. Arkles, B., IPN Modified Silicone Thermoplastics, Med. Dev. Diag. Ind., 5, 1983.
66. Arkles, B., Look What You Can Make Out of Silicones (Biomedical Applications of Silicones), CHEMTECH, 13, 542, 1983.
65. Arkles, B., A Reactive Processing Method for IPN Thermoplastics, Poly. Mat. Sci & Engg., 49, 6, 1983.
64. Arkles, B., Anderson, R., King, K., Silacrowns: Phase Transfer Catalysts, Organometallics, 2, 454, 1983.
63. Arkles, B., Redinger, P. Silicones in Biomedical Devices in “Biocompatible Polymers, Metals and Composites” (M. Szycher ed.) Technomic, Lancaster, p749, 1983.
62. Arkles, B., Silicon Compounds (Ethers and Esters), Kirk-Othmer Encyclopedia of Chemical Technology, 20, 912, 1982.
61. Arkles, B., Peterson, W., Silicon Compounds (Silanes), Kirk-Othmer Encyclopedia of Chemical Technology, 20, 887, 1982.
60. Arkles, B., Peterson, W. R., King, K., A New Class of Immobilizeable Phase Transfer Catalysts: The Silacrowns, in “Chemically Modified Surfaces in Catalysis and Electrocatalysis” (J. S. Miller ed.) Am. Chem. Soc., p. 281, 1982.
59. Arkles, B., New Generation Silicones for Medical Devices, Med. Dev. Diag. Ind. 3(4), 31, 1981.
58. Arkles, B., Peterson, W., High-Heat Silane Coupling Agents, Modern Plastics, 57(11), 69, 1980.
57. Arkles, B., Brinigar, W., Miller, A., Whole Cell and Cell Organelle Immobilization on Silica Substrates, in “Silylated Surfaces” (D. Leyden, W. Collins eds.) Gordon & Breach, New York, p.363, 1980.
56. Arkles, B., Silanes and Silicones in Semiconductors and Microelectronics, SEMICON WEST Proc., 1980.
55. Arkles, B., Peterson, W., New High Temperature Coupling Agents, 35th Soc. Plas. Ind. Composites Inst. Proc., 35, 20-A, 1980.
54. Arkles, B., Peterson, W., The Effect of Silanes on Size-Free Glass Fibers in Thermoplastic Composites, Org. Coat. Plas. Chem, 40, 538, 1979.
53. Arkles, B., Barbecuing - A Scientific Technological Effort, CHEMTECH, 8(8), IBC, 1978.
52. Arkles, B., Tailoring Surfaces with Silanes, CHEMTECH, 7(12), 766, 1977.
51. Theberge, J., Arkles, B., Knabb, D., Molded Plastic Magnets, Machine Design, 49(2), 1977.
50. Theberge, J., Arkles, B., Knabb, D., Magnetic Molding Compounds, 32nd Soc. Plas. Ind Composites Inst. Proc., 32, 14-G, 1977.
49. Arkles, B., Theberge, J., Schireson, M., Wear Behavior of Thermoplastic Polymer Filled Fluorocarbon Composites, Lubrication Engineering, 33(1), 33, 1977.
48. Arkles, B. C., Respiratory Properties Of Rat Liver Mitochondria, Dissertation Abstracts B 1976 No. 99,11,977.
47. Peterson, W., Arkles, B., Washburne, S., Reaction of Trimethylsilyl Azide with Bridged Bicylcic Olefins, J. Organomet, Chem., 121, 285, 1976,
46. Arkles, B., Theberge, J., Schireson, M., Wear Behavior of Thermoplastic Polymer Filled Fluorocarbon Composites, Compressed Air, (12), 1976.
45. Arkles, B., Tailoring Inorganic Surfaces with Organosilanes, Am. Inst. Chem. Eng. Proc., 69, Dec. 1976
44. Theberge, J. E., Cloud, P. J., Arkles, B., Predicting Wear in Reinforced Internally Lubricated Thermoplastics, Plastics World, 34(10), 46, 1976
43. Arkles, B. Schireson, M. J., The Molecular Weight of PTFE Wear Debris, Wear, 39, 177, 1976.
42. Theberge, J., Arkles, B., Robinson, R., Carbon Fiber Reinforced Thermoplastics, Ind. Eng. Chem. Prod. Res. Dev. 15(2), 100, 1976
41. Arkles, B., Brinigar, W. S., Worthy, W., Immobilized Organelles Aid Cell Chemistry,
Chem. Eng. News. 54(2), 17, Feb 9, 1976
40. Arkles, B., Theberge, J., Stronger Thermopastic Elastomers, Machine Design, 48(3), 113, 1976.
39. Arkles, B. Theberge, J., Carreno, C., Designing with Fiber Reinforced and Internally Lubricated Thermoplastic Elastomers, 32nd Soc. Plas. Ind. Composites Inst. Proc., 13-E, 1976.
38. Arkles, B., Brinigar, W., Respiratory Behavior of Rat Liver Mitochondria Immobilized on Alkylsilylated Supports, J. Biol. Chem., 250(22), 8856, 1976.
37. Theberge, J., Arkles, B., Robinson, R., Carbon Fiober Reinforced Thermoplastics,
Soc. Adv. Mat. Proc. Eng. J., 20(11), 72, 1975.
36. Arkles, B., Theberge, J., Cloud, P., Long Term Properties of Thermoplastic Composites, Soc. Plas. Eng., RETECH, 164, Oct. 1975.
35. Arkles, B., Gerakaris, S., Ewan, E., High Performance Functional Powder Coatings, Product Finishing, 40(1), 74-83, 1975.
34. Arkles, B., Theberge, J., Robinson, R., Carbon Fibers Produced Specifically for Discontinuous Reinforcement of Thermoplastics, ACS Org. Coat. Plas. Chem., 36, 10, 1975.
33. Arkles, B., Gerakaris, S., Apply a Function with Powder Coatings, Machine Design, 47(6), 103, 1975.
32. Arkles, B., Ewan, E., Nouvelle Poudres Pour Revetements A Haute Performances, Chimie-Actualities, (5), 40, 1975.
31. Theberge, J., Arkles, B., Cloud, P., How Time and Heat Affect the Properties of Plastics, Machine Design, 47(7), 79, 1975.
30. Theberge, J., Arkles, B., Cloud., P., Choosing Plastics for Chemical Resistance, Machine Design, 47(4), 103, 1975.
29. Theberge, J., Arkles, B., Cloud, P., Comparing High Temperature Plastics, Machine Design, 47(3), 73, 1975.
28. Theberge, J., Arkles, B., Cloud, P., Gerakaris, S., Elevated Temperature Performance of Thermoplastic Composites, 30th Soc. Plas. Ind. Composites Inst. Proc., 17-E, 16pp, 1975.
27. Arkles, B., Peterson, W., Fluoropolymer Solid Lubricants in “Advances in Polymer Friction and Wear” ed. L.H. Lee, Plenum, 453-467, 1974
26. Arkles, B., Gerakaris, S., Goodhue, R., Wear Characteristics of Fluoropolymer Composites in Advances in Polymer Friction and Wear” ed. L. H. Lee, Plenum, 663-688, 1974.
25. Theberge, J., Arkles, B., Wear Characteristics of Carbon Fiber Reinforced Thermoplastics, Machine Design, 46, 1974.
24. Theberge, J., Arkles, B., How Plastics Wear Against Plastics, Machine Design, 46, 1974.
23. Arkles, B., Poly(fluorocarbons) for Powder Coating, Kunststoffe, 64(7), 341-2, 1974.
22. Theberge, J., Arkles, B., Wear Characteristics of Carbon Fiber Reinforced Thermoplastics, Lubric. Eng., 30(12), 585-9, 1974.
21. Arkles, B., Fluoropolymer Solid Lubricants, ACS Org. Coat. Plas. Chem., 34, 326-33, 1974
20. Christian, J. B., Arkles, B., Poly(tetrafluoroethylene) and Fluorinated Ethylene-propylene Grease Lubricants, Lubric. Eng., 30(3), 136-43, 1974.
19. Arkles, B., Fluoplaster for Pulverbelaggning, Plastics World (Sweden), Feb., 1974.
18. Theberge, J., Arkles, B., Robinson, R., Carbon Fibers Add Muscle to Plastics, Machine Design, 46(3), 102, 1974
17. Theberge, J., Arkles, B., Robinson, R., Carbon Fiber Reinforced Thermoplastics, 29th Soc. Plas. Ind. Composites Inst. Proc., 20D, 1974.
16. Arkles, B., Recycling Polytetrafluoroethylene, in “Polymers and Ecological Problems” ed. J. Guillet, Plenum, p121, 1973
15. Arkles, B., Theberge, J., Migratory Internal Lubrication of Thermoplastic Resins, Lubric. Eng., 29(12), 552-5, 1973
14. Theberge, J., Arkles, B., Goodhue, R. New Self-Lubricating Plastics, Machine Design, 45, 56, 1973
13. Arkles, B., Fluoropolymer Coatings, Vinyls and Polymers (Japan), Dec. 1973
12. Arkles, B., Pulberi De Acoperire Fluorocarburi Pseudolichide, Matiale Plastice (Roumania), 10(8), 450, 1973
11. Arkles, B., Fluorocarbon Powder Coatings, The Australian Paint Journal, Sept. 1973.
10. Theberge, J., Arkles, B., Cloud, P., How To Get High Accuracy Plastic Gears, Machine Design, 45, 140, 1973.
9. Theberge, J., Arkles, B., Low Friction and Wear Thermoplastic Composites, ACS Org. Coat. Plas. Chem., 33(2), 188-94, 1973
8. Theberge, J., Arkles, B., Cloud, P., Goodhue, R., Gear and Bearing Design with Lubricated and Reinforced Thermoplastics, 28th Soc. Plas. Ind. Composites Inst. Proc. (RPC Inst.), 5-E, 18pp, 1973
7. Arkles, B., Recycling Polytetrafluoroethylene, ACS Org.Coat. Plas. Chem., 13(2), 812, 1972
6. Theberge, J., Arkles, B., Chemical and Hydrolysis Resistance of Glass Fortified Thermoplastics, Materials Protection and Performance, 11(4), 25, 1972.
5. Arkles, B., Solid Fluorocarbon Lubricants, Nat’l. Lubric. Grease Inst. (NLGI) Spokesman, 35(11), 390-8, 1972
4. Theberge, J., Arkles, B., Cloud, P., Low Cost Glass-Fortified Thermoplastic Resins for Automotive Applications, 27th Soc. Plas. Ind. Composites Inst. Proc., 14-C, 12pp, 1972.
3. Theberge, J., Arkles, B., Cloud, P., Glass Reinforced Thermoplastics, Machine Design, 43, 58, 1971.
2. Theberge, J., Arkles, B., Cloud, P., Thermal and Environmental Resistance of Glass Reinforced Thermoplastics, Machine Design, 43, 1971
1. Theberge, J., Arkles, B., Cloud, P., Environmental, Thermal and Flammability Resistance of Glass Fortified Thermoplastics for Business Machine, Appliance and Tool Housings, 26th Soc. Plas. Ind. Composites Inst. Proc., 3-A, 22pp, 1971.
Barry C. Arkles - Patents
65. Arkles, B., Kimble, E. Low molecular weight siloxanes with one functional group.
European Patent Application, EP 1985645 A2, Oct. 29, 2008.
64. Arkles, B., Pan, Y., Hollenberg, J., Silicon Based Tocopherol Derivatives, US Pat Appl. US 2007/0253925 A1 Nov 1, 2007
63. Arkles, B., Curcumin and its derivatives for use as silicone colorants, US Pat Appl. US 2007/0204412 A1 Sept 6, 2007
62. Arkles, B., Bird-Deterrent Glass Coatings, US Patent Appl.US2007/0190343 A1
August 16, 2007
61. Arkles, B., Pan, Y., Polypodal Silanes with Embedded Hydrophilicity, US Pat 7,265,236, September 4, 2007
60. Kaloyeros, A., Arkles, B., “Method for the Chemical Deposition of Copper-based Films and Copper Sourced Precursors for the Same, Korean Patent 10-0691870, February 28, 2007.
59. Arkles, B., Kaloyeros, A., Methods for the Chemical Vapor Deposition of Titanium-Silicon-Nitride Films, US Application US2006/0088661 A1 April 7, 2006
58. Arkles, B., Kaloyeros, Verfahren zur Herstellung von dünnen Schicten auf Silizium-Stickstoffbasis, DE 198 82 836 B4, April 28, 2005
57. Kaloyeros, A., Arkles, B., Process for Low-Temperature Metal-Organic Chemical Vapor Deposition of Tungsten Nitride and Tungsten Nitride Films. US Pat. 6,884,466, April 26, 2005
56. Arkles, B., Pan, Y., Sulfolane Functional Silanes, Compositions, and Methods of Use of the Same, US Pat. 6,881,849, April 19, 2005
55. Arkles, B., Larson, J., Pan, Y., Preparation of Trialkylsilanes for use on silica in chromatographic Applications, US Pat. 6,800,777, October 5, 2004.
54. Arkles, B., Berry, D.H., b-Substituted Organosilsesquioxane Polymers, US Pat. 6,770,726, August 3, 2004
53. Arkles, B., Pan, Y., Larson, G., Silicon-Based Blocking Agents Suitable for Fluorous Phase Synthesis, US Pat. 6,642,403, Nov. 4, 2003.
52. Arkles, B., Kaloyeros, A., Silicon Based Films formed from Iodosilane Precursors and methods of making the same,” US Pat. 6,589,056, July 1, 2003.
51. Arkles, B., Larson, J., Pan, Y. Chloride-free Process for the Production of Alkylsilanes Suitable for Microelectronic Applications. US Pat.6,410,770, June 25, 2002
50. Kaloyeros, A., Londergan, A., Arkles, B., Method of interlayer mediated epitaxy of cobalt silicide from low temperature chemical vapor deposition of cobalt. US Pat. 6,346,477, Feb. 12, 2002
49. Arkles, B., Kaloyeros, A., Methods for chemical vapor deposition of titanium-silicon-nitrogen films, PCT Int’l Appl. WO 2001079584, 2001
48. Arkles, B., Pan, Y., Larson, G., Production of alkoxysilanes with alkali metal hydrides in chloride-free process, PCT INt’l WO 2001058908, 2001
47. Steinmetz, J., Arkles, B., Method for the Preparation of Stable Water-borne Silane Compositions, EP 01201939.4-2110, July 18, 2001.
46. Kaloyeros, A., Arkles, B., Tantalum and tantalum based films formed using Fluorine-containing Source Precursors and methods for making the same” US Pat. 6,139,922, Oct. 31, 2000
45. Arkles, B., Kaloyeros, A., Chemical Vapor Deposition of Tungsten Nitride,
PCT Int’l WO 2000047404, 2000.
44. Kaloyeros, A. E., Arkles, B.C., Methods for the chemical vapor deposition and preparation of conformal titanium-based films, US Pat., 6,090,709, July 18, 2000.
43. Nau, D., Gan, K., Arkles, B., Sheng, G., Zhou, H., Recovery or organic solutes from aqueous solutions, US Pat. 6,0741,410 (PCT Int’l WO 2000029088), June 6, 2000.
42. Kaloyeros, A., Arkles, B., Method for the Chemical Vapor Deposition of Copper-Based Films and Copper Source Precursors for the same, US Pat. 6,066,196 May 23, 2000.
41. Kaloyeros, A., Arkles, B., Method for the Chemical Vapor Deposition of Copper-Based Films, US Pat. 6,037,001 March 14, 2000.
40. Arkles, B., Kaloyeros, A. Silicon nitrogen-based films and method of making the same, US Pat. 5,968,611 October 19, 1999
39. Arkles, B., Kaloyeros, A. Silicon based films formed from iodosilane precursors and method of making the same, PCT Int’l WO 99 28,529, June 10, 1999
38. Arkles, B.C., Kaloyeros, A. E., Silicon nitrogen-based films and method of making the same precursors and method of making the same. PCT Int’l Appl. WO 99 27,154, June 10, 1999.
37. Arkles, B., Kaloyeros, A. Tantalum and tantalum-based films and methods for making same, US Pat. 5,919,531, July 6, 1999.
36. Arkles, B. Branched Higher Alkylsilanes, US Pat. 5,874,603, Feb. 23, 1999.
35. Arkles, B., Berry, D. Figge, L., Method of Using Siloxane Polymers, US Pat. 5,853,808, Dec. 29, 1998
34. Arkles, B., Kaloyeros, A. Conformal Titanium Based Films and Method for Their Preparation, US. Pat Application. 08/322,020, 1994, PCT Int. Appl. WO 9612048 A2 960425, 1996.
33. Steinmetz, J., Arkles, B., Preparation of Stable Water-borne Silane Compositions, Eur. Pat. Appl. EP 675128 A1, 1995.
32. Arkles, B. Hydroxymethyltriethoxysilane und deren Herstellungs- und Verwendungsverfahtren, Ger. Off. DE 4407 437 A1 15-9-94.
31. Arkles, B. Hydroxymethyltriethoxysilane and Hydrolysis and Condensation Products Derived Therefrom, U.S. Pat. 5,371,262, December 6, 1994
30. Arkles, B., Larsen, G. Preparation of Sterically-Hindered Silanes, U.S. Pat. US Pat. 5,296,624, March 22, 1994.
29. Arkles, B., Hamon, B., Method of Preparing Hexamethylcyclotrisilazane, European Pat. 0,208,831, Jan., 16, 1991
28. Arkles, B., King, K. Silakronether, Verfahren zu ihrer Herstellung und ihre Herstellung und ihre Verwendung, German Patent 32 43 048, Dec. 4, 1990.
27. Arkles, B., Smith, R., Secondary Cross-Linked Semi-Interpenetrating Polymer Networks And Methods of Making Same, U.S. Pat. 4,970,263, Nov. 13, 1990.
26. Arkles, B. Polysilane-Siloxane Oligomers and Copolymers and Methods of Making the Same, Japanese Pat. 1,562,810, June 12, 1990
25. Arkles, B. Chromogenic and Fluorogenic Silanes And Using The Same, U.S. Pat. 4,918,200, April 17, 1990
24. Arkles, B. Curable Silicone Containing Compositions and Methods of Making Same, U.S. Pat. RE 33,070, Sep. 26, 1989
23. Arkles, B. Curable Silicone Semi-Interpenetrating Polymer Networks and Methods of Making Same, U.S. Pat. 4,714,739, Dec. 22, 1987.
22. Arkles, B. C., Brinigar, W. S., Method of Siliconization of Surfaces with Lower Alkyl Silanes, U.S. Pat. 4,711,820, Dec. 8, 1987.
21. Arkles, B. C., Methods of Using Silacrown Ethers as Catalysts, U.S. Pat. 4,699,991, Oct. 13, 1987.
20. Arkles, B. C., Masse aus einem Silicon un einem thermoplastichen Polymer sowie Verfahren zu deren Herstellung, D.E. 3,314,355 C2, April 30, 1987.
19. Arkles, B. C., Pseudointerpenetrating Polymer Networks, U.K. Pat. 2,138,436 B, Feb. 25, 1987.
18. Arkles, B. C., Polysilane-Siloxane Oligomers and Copolymers and Methods of Making the Same, U.S. Pat. 4,626,583, Dec. 2, 1986.
17. Arkles, B. C., N-Methylhydridosilazanes, Polymers Thereof, Methods of making same and silicon nitrides produced therefrom, U.S. Pat. 4,595,775, June 17, 1986.
16. Arkles, B. C., Mixtures of Polyacrylate Resins and Siloxane - Styrene Copolymers, Can. Pat. 1,204,541 May 13, 1986.
15. Arkles, B. C., Hamon, B. N., Method of Preparing Hexamethylcyclotrisilazane, U.S. Pat. 4,577,039, March 18, 1986.
14. Arkles, B., C. Mixtures of Polyacrylate Resins and Siloxane-Styrene Copolymers, U.S. Pat. 4,500,139 Oct. 9, 1985.
13. Arkles, B., Curable Silicone Compositions and Methods of Making Same, U.S. Pat. 4,500,688, Feb. 19, 1985.
12. Arkles, B., Peterson, W. R., Rokowski, J., Mixed Alkoxyaminosilanes, Methods of Making Same and Vulcanizing Silicones Prepared Therefrom. U.S. Pat. 4,491,669, Jan. 1, 1985.
11. Arkles, B., Mixtures of Polyacrylate Resins and Siloxane-Carbonate Copolymers, U.S. Pat. 4,478,981, Oct. 23, 1984.
10. Arkles, B., [2-(p-t-Butylphenyl)ethyl]silanes and Method of Making the Same, U.S. Pat. 4,469,881, Sep. 4, 1984.
9. Arkles, B., Silacrown Ethers, Method of Making Same, and Use as Phase Transfer Catalysts, U.S. Pat. 4,362,884, Dec. 7, 1982.
8. Peterson Jr., W. R., Arkles, B., C., Ethylene Bridged Amine Functional Silanes and Composites Using the Same, U.S. Pat. 4,336,395, June 22, 1982.
7. Arkles, B. C., Peterson Jr., W. R., Method for the Production of Organic Polysilanes,
U.S. Pat. 4,276, 424, June 30, 1981.
6. Arkles, B., Gerakaris, S., Fluorinated Ethylene-Propylene Copolymer Powders Having Improved Adhesion to Substrates, U.S. Pat. 4,110,186, Aug. 29, 1978.
5. Arkles, B., Brinigar, W.S., Bound, Active Cellular Organelles and Method of Making Same, U.S. Pat. 4,078,971, March 14, 1978.
4. Arkles, B., Bonnet, R., Super-heated Steam Depolymerization of Polytetrafluoroethylene, U.S. Pat. 3,832,41, Sept., 1974.
3. Arkles, B., Glass-Reinforced Thermoplastics with Metallocene Coupling Agents, US Pat. 3,760,131, Oct. 1973
2. Arkles, B., Glass Fiber Stengthened Thermoplastics, Germ. Off., DE 2223022, Dec., 1972.
1. Arkles, B., Bonnet, R., Depolymerization of Polytetrafluoroethylene, Germ. Off.
DE 2204141, Aug. 17, 1972
Gerald L. Larson - Publications
G. Larson, “Key Organosilane Reductions”, Specialty Chemicals Magazine, September 2008, 28, 54.
B. Arkles, G. L. Larson, “Silicon Compounds: Silanes & Silicones” Gelest Catalog, Gelest, Inc. 2008.
G. L. Larson, “1-Aza-2,5-disila-2,2,5,5-tetramethylcyclopentane” in e-EROS, John Wiley and Sons 2008.
G. L. Larson, “Vinyltrimethylsilane” in e-EROS, John Wiley and Sons 2007.
G. L. Larson, J. L. Fry, “Ionic and Organometallic-Catalyzed Organosilane Reductions”, in Organic Reactions S. E. Denmark, Ed. Volume 71, John Wiley and sons, pp 1-771, 2008.
G. L. Larson, “Silicon-Based Reducing Agents”. Version 2.0, Gelest, Inc. 2008.
G. L. Larson, “Silicon-Based Blocking Agents”,Version 3.0 Gelest, Inc. 2006.
B. Arkles, Y. Pan, G. L. Larson, D. H. Berry, “Cyclic Azasilanes: Volatile Coupling Agents for Nanotechnology”, Silanes and Other Coupling Agents, Vol. 3, Ed. K. L. Mittal, pp 179-191, 2004
- Ricci, G. C. Seconi, R. Curci, G. L. Larson, "Organosilyl Peroxides", in Advances in Silicon
Chemistry, Vol 3, G. L. Larson, ed. JAI Press, Greenwich, CT USA.
G. L Larson, "The Chemistry of a-Silyl Carbonyl Compounds" in Advances in Silicon Chemistry, Vol 3, G. L. Larson ed. JAI Press, Greenwich, CT. USA.
G. L. Larson “Silicon-Based Cross-Coupling Reactions”, 2008, Gelest, Inc.
R. Chawla, G. L. Larson, “Preparation of 1,1,3,3-Tetraisopropyl-1,3-dichlorodisiloxane and Triispropylchlorosilane”, Synthetic Commun. 29, 3499, 1999.
G. L. Larson, R. R. Chawla, C. S. Subramaniam, T. V. John, "A Commercially Viable Synthesis of Cyanotrimethylsilane", Org. Proc. Res. Dev., 1, 90 (1997).
G. L. Larson, "Ethyl a-(Methyldiphenylsilyl)acetate", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.
G. L. Larson, "Ethyl a-(Methyldiphenylsilyl)propionate", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.
G. L. Larson, "N,N-Dimethyl-2-(trimethylsilyl)acetamide", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.
G. L. Larson, "Trimethylsilylacetone", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.
G. L. Larson, "Methyldiphenylchlorosilane", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.
G. L. Larson, "Trimethylsilyl-t-butylamine", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.
T. J. Delord, F. R. Fronczek, R. M. Betancourt de Perez, G. L. Larson, "Structure of an a-(Methyldiphenylsilyl)-g-lactone", Acta Cryst., C49, 1799 (1993).
J. A. Prieto, M. T. Pallares, G. L. Larson, "Preparation and Reactions of Ethyl 1-(Diphenyl-methylsilyl)cyclopropane Carboxylate", Synlett., 199 (1993).
G. L. Larson, F. C. Cartledge, R. Nunez, R. J. Unwalla, R. Klesse, L. Del Valle, "The Preparation of (a,a-Dichlorobenzyl)silanes and (a-Halobenzyl)silanes" Organometallics, 11, 859 (1992).
G. L. Larson, Editor "Advances in Silicon Chemistry" Volume 1, 1992.
G. L. Larson, "Silicon The Silicon-Carbon Bond: Annual Survey for the Year 1989, J. Organometal. Chem., 1991.
G. L. Larson, "Trimethylsilyldiazomethane", Silicon Compounds, Register and Review, Hüls America, Inc., 1991.
G. L. Larson, "Trimethylsilylnitrile", Silicon Compounds, Register and Review, Hüls America, Inc., 1991.
G. L. Larson, "Trimethylsilyl Iodide", Silicon Compounds, Register and Review, Hüls America, Inc., 1991.
G. L. Larson, "Silicon The Silicon-Carbon Bond: Annual Survey for the Year 1988, J. Organometal. Chem., 1991.
F. R. Fronczek, G. L. Larson and J. Suarez, "Racemic tert-Butyl-(1-Naphthylphenylmethyl-silyl) Acetate", Acta Cryst., C46, 2480 (1990).
G. L. Larson, "a-Silyl Carbonyl Compounds" Pure and Applied Chemistry, Pure and Applied Chemistry, 62, 2021 (1990).
G. L. Larson, J. A. Soderquist, M. Rivera Claudio, "Preparation of b-Silyl-a,b-Unsaturated Esters and 3-Silyl Allyl Alcohols", Synthetic Commun., 20, 1095-1104 (1990).
G. L. Larson, "Silicon-The Silicon-Carbon Bond: Annual Survey for the Year 1987", J. Organometal. Chem., 374, 1 (1989).
G. L. Larson, "Silicon The Silicon-Carbon Bond: Annual Survey for the Year 1986, J. Organometal. Chem., 360, 39 (1989).
G. L. Larson, J. A. Prieto, P. Gonzalez, "A Synthesis of Fused Butenolides", Synthetic Commun., 19, 2779 (1989).
J. A. Prieto, G. L. Larson, P. Gonzalez, "The Stereochemistry of the Reaction of a-Silyl Lithium Reagents with Cyclic Tert-Butyldimethylsilyl Acyloins", Synthetic Commun. 19, 2773 (1989).
G. L. Larson, J. A. Prieto, L. del Valle, "The Reaction of a,a-Dichloro-benzyltrimethylsilane with Some Aldehydes and Ketones", Synth. Commun., 19, 1405 (1989).
G. L. Larson, "Recent Synthetic Applications of Organosilanes" in The Chemistry of Organic Silicon Compounds S. Patai and Z. Rappoport, eds. John Wiley & Sons, Ltd. 1989, Chapter 11 pp 764-808.
J. A. Prieto, G. L. Larson, R. Berrios, "A Regio- and Stereoselective Synthesis of Enol (Methyldiphenylsilyl) Ethers", Tetrahedron Lett., 30, 283 (1989).
G. L. Larson, J. A. Prieto, E. Ortiz, "The Preparation and Chemistry of (R)-(1-Naphthyl)-phenylmethylsilylmethyllithium: Stereochemistry at Silicon in the Elimination of b-Hydroxysilanes", Tetrahedron, 44, 3781 (1988).
C. L. Barnes, G. L. Larson., A. Santiago, J. Rios Steiner, "Ethyl 3-(2-Methyl-1,3-dioxolan-2-yl)-2-(methyldiphenylsilyl)propionate", Acta Cryst. C44, 1323 (1988).
C. L. Barnes, G. L. Larson, Y. -S. Lee, "Trans 1,1,2,5-tetraphenyl-1-silacyclopentane", Acta Cryst., C44, 1148 (1988).
G. L. Larson, C. L. Barnes, S. B. Sandoval, "Trans -1,2,5-triphenyl-1-silacyclopentane", Acta Cryst., C44, 1147 (1988).
J. A. Prieto, G. L. Larson, R. Berrios, A. Santiago, "A Silicon Facilitated Preparation of 1,3 Dienes", Synthetic Commun., 18, 1385 (1988).
G. L. Larson, "Organosilanes in Organic Synthesis" VIIIth International Symposium on Organosilicon Chemistry, St. Louis, MO 1987.
G. L. Larson (with B. Arkles and R. Anderson) editor of "Silicon Compounds, Register and Review", Petrarch Systems, 1987.
W. R. Peterson, R. Anderson, G. L. Larson, "Silane Blocking Agents", Silicon Compounds, Register and Review, Petrarch Systems, 1987.
G. L. Larson, "An Introduction to Organosilicon Chemistry", Silicon Compounds, Register and Review, Petrarch Systems, 1987.
J. A. Prieto, J. Suarez and G. L. Larson, "The Regioselectivity of Deprotonation of Unsymmetrical Ketones with Lithium Tert-Butyltrilakylsilyl Amides", Synthetic Commun., 18, 253 (1988).
E. Torres, G. L. Larson and G. J. McGarvey, "An Asymmetric Hydrogen Equivalent: Use of the 1-Napthylphenylmethylsilyl Group in the Synthesis of Optically Active Allyl Alcohols and 1-Phenyl-1,2-Butadiene", Tetrahedron Lett., 29, 1355 (1988).
G. L. Larson, V. Cruz de Maldonado, L.M. Fuentes and L.E. Torres, "The Methyldiphenyl-silylation of Ester and Lactone Enolates", J. Org. Chem., 53, 633 (1988).
G. L. Larson, I. Montes de Lopez-Cepero and L. Rodriguez, "a-Diphenyl-methylsilylation of Ester Enolates: 2-Methyl-2-Undecene from Ethyl Decanoate", Organic Synthesis, 67, 125 (1988).
G. L. Larson, R. Klesse and F.K. Cartledge, "Thermal Rearrangement of (S,S)-1-Naphthyl-phenylmethyl(1-chloroethyl)silane and (S)-(1-Chloro-ethyl)phenyldimethylsilane", Organometallics, 6, 2250, 1987.
M. A. de Jesus, J. A. Prieto, L. del Valle, G. L. Larson, "Trichloromethyl-anion Chemistry from Trimethylsilyl Trichloroacetate", Synthetic Commun., 17, 1047 (1987).
Y. -S. Lee, L. del Valle, G. L. Larson, "A Ready Preparation of 2-(2-Iodoethyl)-1,3-dioxane: A Facile three-Carbon Extension of Grignard Reagents", Synthetic Commun., 17, 385 (1987).
G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for the year 1985", J. Organometal. Chem. 337, 195-430 (1987).
V. Cruz de Maldonado and G. L. Larson, "The (Methyldiphenylsilylation) of Carboxylic Acid Dianions", Synthetic Commun., 16, 1347 (1986).
L. E. Torres and G. L. Larson, "The Palladium (II)Acetate-Mediated 6-Endo-Trig Cyclization of 1,1-Dialkyl-2-Silyloxy-1,5-Dienes", Tetrahedron Lett., 27, 2223 (1986).
G. L. Larson, E. Torres, C. Burgos Morales, G. J. McGarvey, "The Preparation and Reactions of (E) a-Lithio-a-(Methyldiphenylsilyl) Alkenes", Organometallics, 5, 2274 (1986).
R. M. Betancourt de Perez, G. L. Larson, C. L. Barnes and M. J. Heeg, "A Synthesis of 4-Oxo Carboxylic Acids, 4-Oxo Aldehydes, and 1,4-Diketones from g-Lactones", J. Org. Chem., 51, 2039 (1986).
G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for the year 1984, J. Organomet. Chem. (Book-Chapter), 313, 141 (1986).
G. L. Larson, A. Santiago and I. Montes de Lopez-Cepero, "A Synthesis of 2,2-Ethylenedioxy 6-Ketones", Synthetic Commun. 16, 697 (1986).
G. L. Larson, A. Santiago and I. Montes de Lopez-Cepero, "A Synthesis of 2,2-Ethylenedioxy 5-Ketones", Synthetic Commun., 16, 705 (1986).
G. L. Larson, D. Hernandez, I. Montes de Lopez-Cepero and L. E. Torres, "The Reaction of Alpha (Diphenylmethylsilyl) Esters with Grignard Reagents: A Synthesis of b-Ketosilanes and Ketones. The Synthesis of the Douglas Tussock Fir Moth Pheromone", J. Org. Chem., 50, 5260 (1985).
G. L. Larson and R. M. Betancourt de Perez, "A Two-Step Preparation of a-Ylidene Gamma Lactones From g-Lactones: A Synthesis of Racemic Ancepsenolide", J. Org. Chem., 50, 5257 (1985).
G. L. Larson and R. Klesse, "An Improved Synthesis of the Ethylene Acetal of 3-Iodopropanal and The Ethylene Ketal of 4-Iodo-2-butanone", J. Org. Chem., 50, 3627 (1985).
G. L. Larson and E. Torres, "Asymmetric Induction by Chiral Silicon Groups", J. Organometal. Chem., 293, 19, (1985).
G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for 1983", J. Organometal. Chem. Libr., 17, pp 1-162 J. Oliver Ed., Elsevier Publishing Co., New York, (1985) (Book-Chapter).
G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for 1982", J. Organometal. Chem., 274, 29 (1984) (Book-Chapter).
G. L. Larson, "a-Silyl Carbonyl Compounds: Synthesis and Characterization", "Silicon Compounds: Register and Review", Petrarch Systems, Inc. Bristol, PA. 22 (1984) Review.
G. L. Larson, J. Organometallic Chem. Libr., 14, 267 J. Oliver and R. B. King Eds., Elsevier Scientific Publishing Co., New York, (Book-Chapter).
G. L. Larson and D. Hernandez, "The Synthesis of Tri- and Tetra-Substituted Olefins From Alpha Silyl Esters", J. Org. Chem., 49, 4285 (1984).
G. L. Larson, C. Fernandez de Kaifer, R. Seda, L. E. Torres and J. R. Ramirez, "A Stereo-selective, Two-Step Preparation of a-Alkyl, a, b-Unsaturated Esters", J. Org. Chem., 49, 3385 (1984).
G. L. Larson, I. Montes de Lopez-Cepero and L. E. Torres, "An Efficient Synthesis of Beta Ketosilanes" Tetrahedron Lett., 25, 1673 (1984).
G. L. Larson and V. Cruz de Maldonado, "A Silicon Mediated Conversion of Esters to Terminal Olefins and Specifically Deuterated Olefins", Synthetic Commun., 13, 1163 (1983).
G. L. Larson, F. Quiroz and J. Suarez, "Studies on the Stereoselectivity of the Preparation of a, b-Unsaturated Esters from a-Lithio a-Silyl Esters", Synthetic Commun., 13, 833 (1983).
G. L. Larson, J. Organometallic Chem. Libr., 13, 387 J. Oliver and R. B. King, Eds., Elsevier Scientific Publishing Co., New York 1983. (Book-Chapter)
G. L. Larson, S. Sandoval, F. Cartledge and F. R. Fronczek, "a-Haloethylsilanes Optically Active at Carbon and at Silicon: Synthesis and Absolute Configuration", Organometallics, 2, 810 (1983).
G. L. Larson and J. A. Prieto, "Entries into Prostanoid Models via the Hydroboration of Enol Silyl Ethers", Tetrahedron, 39, 855 (1983).
G. L. Larson and C. Cadiz, "Attempted Generation of Halocarbenes: Protodesilylation of Dihalomethylsilanes", J. Organometal. Chem. 232, 113-116 (1982).
G. L. Larson and M. Ortiz, "The Reaction of Sulfonyl Azides With Organoboranes", Synthetic Commun., 12, 43 (1982).
G. L. Larson and D. Hernandez, "Facile Synthesis of Symmetrical 1,1-Disubstituted Ethylenes", Tetrahedron Lett., 23, 1035, (1982).
L. M. Fuentes and G. L. Larson, "A Facile Synthesis of 4-oxo Carboxylic Acids From g-Butyrolactone", Tetrahedron Lett., 23, 271 (1982).
L. del Valle, S. Sandoval and G. L. Larson, "The Preparation of a, a-Dichloromethylsilanes Under Phase Transfer Conditions", J. Organomet. Chem., 215, C45 (1981).
G. L. Larson, M. Ortiz, M. Rodriguez de Roca, "The Reaction of Tri-methylsilyl Esters with Metal Hydride Reducing Agents. Protection of Carboxylic Acids as Their Trimethylsilyl Esters During Hydroboration", Synthetic. Commun., 11, 583 (1981).
G. L. Larson, J. A. Prieto and A. Hernandez, "Thermodynamic and Kinetic Control in the Reaction of Carboethoxymethylenetriphenylphosphorane and Ethyl Lithiotrimethylsilyl-acetate with 2-(tert-Butyldimethylsilyloxy)cycloalkanones", Tetrahedron Lett., 22, 1575 (1981).
G. L. Larson and L. M. Fuentes, "The C-Silylation of Lithium Ester Enolates", J. Am. Chem. Soc., 103, 2418 (1981).
G. L. Larson and L. del Valle, "The Reaction of Silanes with Chloroform Under Phase Transfer Conditions: An Unfortunate, Convenient Preparation of Disiloxanes" Syn. React. Inorg. Metal. Org. Chem., 11, 173 (1981).
A. Oliva and G. L. Larson, "Sintesis y Propiedades Espectrales de 1-(Arildimetilsilil)-2 propanonas y 2-(Arildimetilsiloxi)propenos", Rev. Latinoamer. Quim., 11, 143 (1980).
O. Rosario, S. Sandoval and G. L. Larson, "The Reaction of (Phenyldimethylsilyl)dichloro-methyllithium with Organoboranes. A Synthesis of a-Hydroxyorganosilanes and Ketones", Synthetic Commun., 10, 813 (1980).
J. A. Prieto and G. L. Larson, "Preparation of Trans-2-Acyl Cyclopentanols and Cyclo-hexanols", Synthetic Commun., 10, 675 (1980).
G. L. Larson, R. Arguelles, O. Rosario and S. Sandoval, "The Preparation of a-Hydroxy-organosilanes from Alpha Boryl Organosilyl Intermediates", J. Organomet. Chem., 198, 15 (1980).
R. S. -C. Tsai, G. L. Larson and A. Oliva, "A Mass Spectral Study of 1-(Aryldimethylsilyl)-2-Propanones and Their Isomeric 2-(Aryl- dimethylsilyl)-1-Propenes", Org. Mass Spec., 14, 364 (1979).
G. L. Larson and L. Fuentes, "A Reductive 1,2-Transposition of Acyclic Ketones", Synthetic Commun., 9, 841 (1979).
G. L. Larson and O. Rosario, "The Formation and Alkylation of (Tri-methylsilyl), (Phenyl-dimethylsilyl)- and (Diphenylmethylsilyl)- Dichloromethyllithium. Preparation of a, a-Dichloroalkylsilanes and ((Z)-1-Chloro-1-alkenyl)silanes",
J. Organomet. Chem., 168, 13 (1979).
A. Oliva and G. L. Larson, "The Reaction of Chloromethylsilanes with Lithium Diisopropyl-amide", Rev. Latinoamer. Quim., 10, 54 (1979).
J. D. White and G. L. Larson, "The Reduction of Organic Substrates with Ytterbium-Ammonia Solution", J. Org. Chem., 43, 4555 (1978).
O. Rosario, A. Oliva and G. L. Larson, "A Synthesis of a-Hydroxysilanes", J. Organomet. Chem., 146, C8 (1978).
M. de Jesus, O. Rosario and G. L. Larson, "The Hydroboration-Oxidation of the Isomeric Trimethylsilylcyclohexenes and the Isomeric Trimethylsilylcyclopentenes", J. Organomet. Chem., 132, 301 (1977).
G. L. Larson, V. Nemeth and H. Valente, "A Convenient Synthesis of Arylsilanes from Chloro-benzenes", Syn. React. Inorg. Metalorg. Chem., 6, 21 (1976).
G. L. Larson and A. Hernandez, "The Stereochemistry of the b- Elimination of b-Trimethyl-siloxy Organoboranes", J. Organomet. Chem., 102, 123 (1975).
G. L. Larson, E. Hernandez, C. Alonso and I. Nieves, "A Synthesis of Olefins via Hydroboration of Cyclic Trimethylsilyl Enol Ethers", Tetrahedron Lett., 4005 (1975).
G. L. Larson and O. Rosario, "A Synthesis of a, b-Unsaturated Esters via Ethyl Lithio-trimethylsilylacetate", Rev. Latinoamer. Quim., 6, 16 (1975).
G. L. Larson and Y. V. Fernandez, "The Mechanism of the Thermal Rearrangement of Beta Ketosilanes", J. Organomet. Chem., 86, 193 (1975).
G. L. Larson, D. Hernandez and A. Hernandez, "The Hydroboration of Trimethylsilyl Enol Ethers", J. Organomet. Chem., 76, 9 (1974).
G. L. Larson and A. Hernandez, 'The Reaction of Trimethylsilyl Enol Ethers with 2-Mercapto-ethanol", Synthetic Commun., 4, 61 (1974).
G. L. Larson and A. Hernandez, "The Reaction of Trimethylsilyl Enol Ethers with Diols", J. Org. Chem., 38, 3935 (1973).
D. S. Matteson and G. L. Larson, "Tin and Lead Derivatives of tetrakis(dimethoxyboryl)-methane", J. Organomet. Chem., 57, 225 (1973).
R. T. Gray, J. Diekman, G. L. Larson, W. K. Musker and C. Djerassi, "Electron-Impact Induced Fragmentations and Rearrangements of Alkoxycyclohexanol Trimethylsilyl Ethers and Alkoxycyclohexyl Trimethylsilanes", Org. Mass Spec., 3, 973 (1970).
D. S. Matteson, R. B. Castle and G. L. Larson, "Tetrakis(acetoxymercury)methanes", J. Am. Chem. Soc., 92, 231 (1970).
D. S. Matteson and G. L. Larson, "Boron-Tin and Boron-Lead Tetrametallomethanes", J. Am. Chem. Soc., 91, 6541 (1969).
W. K. Musker and G. L. Larson, "The Stereochemistry of the Beta Elimination Reactions in Organosilanes", J. Am. Chem. Soc., 91, 514 (1969).
W. K. Musker and G. L. Larson, "Synthesis of the Cis and Trans Isomers of 2-Trimethylsilyl-cyclohexanol", Tetrahedron Lett., 3481 (1968).
W. K. Musker and G. L. Larson, "Intramolecular Interactions Involving Group IV Elements. Spectral Properties of 1-(Trimethylsilyl)-2-Propanone", J. Organomet. Chem., 6, 627 (1966).
Gerald L. Larson - Patents
G. L. Larson, R. R. Chawla, “Herstellung von Substituierten (Amino)dialkoxysilanen”, (“Preparation of Substituted (Amino)dialkoxysilanes”), EP 1 062 220 B, May 4, 2006.
Al-J. Frings, G. L. Larson, A. Edinger, “3-Methacryloxy- und 3-Acryloxyisobutylalkoxysilane”, EP 1004587, May 19, 2005
B. C. Arkles, G. L. Larson, Y. Pan, “Trialkylsilanes for Use in Chromatographic Applications, Substrates Including Such Compounds and Methods of Producing Same”, US 6,800,777, October 5, 2004
G. L. Larson, et al., “3-Methacryloxy- and 3-Acryloxyisobutylalkoxysilane”, US 6,608225.
B. C. Arkles, Y. Pan, G. L. Larson, “Azasilanes and Methods for Making and Using Same”, applied for 4, 03.
B. C. Arkles, Y. Pan, G. L. Larson, "Silicon-Based Blocking Agents Suitable for Fluorous Phase Synthesis", US 2003/0092927 A1, May 15, 2003
B. C. Arkles, G. L. Larson, Y. Pan, "Trialkylsilanes for Use in Chromatographic Applications, Substrates Including Such Compounds and Methods of Producing Same", US 6,800,777.
B. Arkles, Y. Pan, G. Larson, "Chloride-Free Process for the Production of Alkylsilanes suitable for Microelectronic Applications", US 6,410,770; DE 101 95 358 T1.
G. L. Larson, R. Chawla, “Preparation of Alkyl(amino)dialkoxysilane”, US 6,114,558, (September 5, 2000).
G. L. Larson, R. Chawla, “Preparation of Acyloxysilanes”, US 5,902,892, (May 11, 1999).
T. V. John, G. L. Larson, C. S. Subramaniam, “Process for Producing Cyanoformate Esters”, US 5,852,207, (Dec. 22, 1998).
G. L. Larson, J. Zazyczny, L. E. Linder, “Preparation of Waterborne Silane/Titanium Chelates Composition, US 5,796,117, (1998).
C. S. Subramaniam, G. L. Larson, "Synthesis of Silyl Cyanohydrins", US 5,594,156, (1997).
S. E. Wilson, G. L. Larson, P. N. Hazin, "Olefinpolymerisationskatalysator", EP 0,611,779 (1994).
G. Bernhardt, M. Haas, H. Kragl, G. L. Larson, "Pyridinium Salts Containing Alkoxysilyl Groups", US 5,371, 216 (1994).
G. Bernhardt, M. Haas, H. Kragl, G. L. Larson, "Pyridinium Salts Containing Alkoxysilyl Groups", US 5,235, 051 (1994).
G. L. Larson, T. V. john, R. R. Chawla, C. S. Subramaniam, "Preparation of Trialkylsilyl Nitriles", US 5,258,534 (1992).
G. L. Larson, B. Arkles, "Preparation of Sterically-Hindered Silanes", US 5,296,624 (1992).
Yun Mi Kim - Publications
Y. Kim, S. Farrah, R. H. Baney “Structure-Antimicrobial Activity Relationship for a New Class of Antimicrobials, Silanols, in Comparison to Alcohols and Phenols”, International Journal of Antimicrobial Agents, 29 (2007) 217-222.
Y. Kim, S. Farrah, R. H. Baney “Membrane damage of bacteria by silanols treatment” , Electronic Journal of Biotechnology, Vol 10(2), 252-259, 2007, Times Cited 1.
Y. Kim, S. Farrah, R. H. Baney “ Silanol – A Novel Class of Antimicrobial agent”, Electronic Journal of Biotechnology, Vol 9(2), 176-180, 2006, Times Cited 2.
YM. Kim, R. Baney, K. Powers, B. Koopman, J. Tulenko, “Screening experiments for removal of low-level tritiated water ” Nuclear Technology, Vol. 149(3), p. 337-342, 2005, Times Cited 1.
Youlin Pan - Publications
The Role of Polarity in the Structure of Silanes Employed in Surface Modification B. Arklis, Y. Pan, Y. Kim “Silanes and Other Coupling Agents” Vol 5, Edited by K. L. Mittal, VSP Publishers, Utrecht, 2009.
Cyclic Azasilanes: Volatile Coupling Agents for Nanotechnology. B. Arklis, Y. Pan, G. Larson, D. H. Berry: “Silanes and Other Coupling Agents” Vol 3, Edited by K. L. Mittal, VSP Publishers, Utrecht, 2004.
Silole: Syntheses and Chemistry, Y. Pan “Silicon Compounds: Silanes and Silicones”
Edited by Barry Arklis & Gerald Larson, Publisher, Gelest Inc., 2004.
Mechanistic Studies of the reaction of Hydrosiloles with Nucleophiles. Crystal
Structures of the Enantiomers of 1-Methyl-2-(dimethylsilyl)-2,3,4,5-
tetraphenyl-1-silacyclo-3-pentene and 1-(Bis(trimethylsilyl)amino)-5-methyl-2,3,4,5-tetraphenyl-1-silacyclo-3-pentene S. B. Choi, P. Boudjouk, Y. Pan, Organometallics.,18, 1999, 3813.
Surprising Reaction of Non-Nucleophilic Bases with 1-Hydrosiloles: Addition and
Not Deprotonation. Y. Pan, J. H. Hong, S. B. Choi and P. Boudjouk, Organometallics., 16, 1997, 1445.
A Novel Lithocenophane Derivative of a Trisgermole Dianion: {Li+•[(2,3,4,5-tetraethyl-germole)2]-(2,3,4,5-tetraethylgermole)}•{[Li+](TMEDA)(THF)}. J. H. Hong, Y. Pan, and P. Boudjouk, Angew. Chem., 35, 1996, 186
Phenylated Group 13/15 Compounds: Convenient Precursors To Phase Pure Gallium Arsenide And Gallium Phosphide. Y. Pan and P. Boudjouk, Main Group Chemistry, 1, 1995, 61.
Disilane und ein Disilen mit unsymmetrischer Substitution an den Siliciumatomen.
M. Weidenbruch, A. Pellmann, Y. Pan, S. Pohl and W. Saak, J. Organomet. Chem., 450, 1993, 67.
Novel Reactivity of d10-d10 Palladium Complex. R. Landtiser, Y. Pan and M. J. Fink, Phosphorus, Sulfur, and Silicon and the Related Elements, 93-94, 1993, 393.
Synthesis, Structure, and Unusual Reactivity of d10-d10 Palladium(0) Dimer. Y. Pan, J. T. Mague and M. J. Fink, J. Am. Chem. Soc., 115, 1993, 3842.
Stable Bissilyl Palladium Complexes: Synthesis, Structure, and Bissilyation of Acetylenes. Y. Pan, J. T. Mague and M. J. Fink, Organometallics, 11, 1992, 3495.
The Synthesis and Properties of Si=Si Double Bond Compounds. Y. Pan and
Y. Wang, Daxue Huaxue, 11, 1996, 41
Why Si=Si Double Bond Compounds are So Difficult to Synthesize. Y. Pan and Y.
Wang, Daxue Huaxue, 6, 1991, 46.
A Spirocyclic Silane from a 2,2-Dimesityldisilanes. M. Weidenbruch, Y. Pan, K. Peters and H. G. von Schnering, Chem. Ber., 123, 1990, 795.
A Bicyclic Disilane from the Reaction of 1,2-Dichlorotetramesityldisilane with
Lithium tert-Butyl Amide. M. Weidenbruch, Y. Pan, K. Peters and H. G. von
Schnering, Chem. Ber., 122, 1989, 1483.
Reactions of 1,2-Dihalodisilanes with Alkali Metal Amides: Formation and Structure of a Tetrahydrodibenzo[b,f][1,5]-disilocine. M. Weidenbruch, Y. Pan, K. Peters and H. G. von Schnering, Chem. Ber., 122, 1989, 885.
Youlin Pan - Patents
Silicon–Based Tocopherol Derivatives B. Arklis, Y. Pan, J. Hollenburg U. S. Patent, 0253925, A1, 2007.
Azasilanes and Methods for Making and Using the Same. B. Arklis, Y. Pan,
G. Larson, U. S. Patent, 0232822, A1, 2007.
Polypodol Silanes with Embolden Hodrophilicity. B. Arklis, Y. Pan, U. S. Patent, 7265236, B2, 2007.
Sulfolane functional silanes, compositions, and methods of use of the same, B. Arklis, Y. Pan. U. S. Patent, 6881849,B2 2005
Trialkylsilanes for use in chromatographic applications, substrates including such
compounds and methods of producing the same, B. Arklis, G. Larson, Y. Pan
U .S. Patent, 6800777, B2, 2004.
Silicon-based blocking agents suitable for fluorous phase synthesis. B. Arklis,
Y. Pan, G. Larson. U. S. Patent, 6642403, B2, 2003.
Chloride-free process for the production of alkylsilanes suitable for microelectronic
applications. B. Arklis, Y. Pan, G. Larson, U. S. Patent, 6410770, B2, 2002.
Joel Zazyczny - Publications
DIPODAL SILANES: ENHANCED SUBSTRATE ADHESION, J.M. Zazyczny & B. Arkles; Adhesives and Sealants Industry, November 2008
TAILORING INORGANIC FOR HIGH PERFORMANCE APPLICATIONS, J. M. Zazyczny & Yun Mi Kim; InterTech Pira, High Performance Pigements, November 2007
TAILORING THE DISPERSION AND WETTING PROPERTIES OF INORGANIC SUBSTRATES WITH ORGANOSILANES, Yun Mi Kim, Joel Zazyczny, Youlin Pan, Barry Arkles, Jane Hollenberg, and Gerald L. Larson; InterTech Pira High Performance Pigments, November 2007
PVC HANBOOK, CHAPTER 7, Fillers & Reinforcing Agents: J.M. Zazyczny & L. Matuana;
Hanser Publishers, Munich, Hanser Gargner Publications, Cincinnati, 2005.
REINFORCING TPO COMPOUNDS: AN INVESTIGATION OF FUNCTIONAL FILLERS: J. M. Zazyczny & Joseph Z. Keating, SPE Automotive TPO Global Conference, October, 2001.
FUNCTIONAL FILLERS EFFICACY IN TPO COMPOUNDS: J. M. Zazyczny & J. Z. Keating; TPOs in Automotive, October 2000.
MINERALS EFFECT ON COLOR IN PLASTIC COMPOUNDS: J. M. Zazyczny; PMAD RETEC, Your Ticket To Outstanding Color and Additives, September, 2000.
MINERALS: FORM AND FUNCTION IN PLASTICS: J.M. Zazyczny, Functional Fillers & Reinforcements; Intertec Conference, September 1999.
FUNCTIONAL MINERAL FILLERS FOR POLYOLEFINS: A LOOK AT TALC AND MICA: J.M. Zazyczny and J.Z. Keating, Polyolefins XI, The International Conference on Polyolefins, February, 1999.
INTERACTIVE MINERALS FOR THE 21ST CENTURY: J.M. Zazyczny. PMAD RETEC, Polymer Additives: What’s New and Review, October, 1997.
WATER-BORNE SILANE COUPLING AGENTS FOR ADHESIVES AND SEALANTS: J.M. Zazyczny and J.R. Steinmetz, The Journal of The Adhesive and Sealant Council, Inc., Volume XXII, No. 2 1993.
SILANES AND OTHER COUPLING AGENTS: Edited K.L. Mittal “Factors Contributing to the Stability of Alkoxysilanes in Aqueous Solutions”: B. Arkles, J.R. Steinmetz, J. Zazyczny and P. MehVSP BV The Netherlands, 1992.
FACTORS CONTRIBUTING TO THE STABILITY OF ALKOXY SILANES IN AQUEOUS SOLUTIONS: B. Arkles, J.R. Steinmetz and J. Zazyczny, Journal of Adhesion Science and Technology, 1992.
STABLE, WATER BORNE SILANE COUPLING AGENTS: B. Arkles, J.R. Steinmetz, J. Zazyczny and M. Zolotnitsky, Society of Plastics Industry, Inc. February 18, 1991.
Joel Zazyczny - Patents
“Lubricant Package for CaCO3 Filled PVC”, US Patent Pending Ref. 04932/US, Filing Date: August 4, 2008.
“Impact Resistant PVC Formulations and Methods of Manufacturing Thereof”, US Patent Pending Ref. 1119B/US, Filing Date: November 1, 2005.
“Preparations of Waterborne Silane/ Titanium Chelates Composition”, US Patent No. 5,796,117, Date of Issue: August 18, 1998.
“Preparation and Use of Alyleneoxy-Silane Compositions”, US Patent No. 5,629,437
Date of Issue: May 13, 1997.
“Preparation and Use of Alyleneoxy-Silane Compositions”, Canadian Patent No. CA 2196232, Date of Issue: April 22, 1997.
“Preparation and Use of Alyleneoxy-Silane Compositions”, European Patent No. 97101368.5-2110, Date of Issue: April 22, 1997.
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