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SILICON CHEMISTRY

Introduction and Review Articles

An Organosilicon Chemistry Primer (105 Kb)

Naming Silicon Compounds (61 Kb)

Silicon Esters (692 Kb)

Silylenes, Silylenium Ions, and Multiply Bonded Silicon Compounds (294 Kb)

Polyhedral Oligosilsesquioxanes and Heterosilsesquioxanes (966 Kb)

Silole and Its Anions (163 Kb)

New Starting Materials for Silicones and Carbosilanes (402 Kb)

Bond Dissociation Energies in Organosilicon Compounds (2,242 Kb)

Grignard Reagents and Silanes (136 Kb)

a,β-epoxysilanes (3.1 MB)

Chemistry of α-Silyl Carbonyl Compounds (4.6 MB)

Chemistry of Trialkylsilyl Perfluoroalkane Sulfonates Part 1 (1.7 MB)

Chemistry of Trialkylsilyl Perfluoroalkane Sulfonates Part 2 (1.5 MB)

Dehydrogenative Coupling Reactions of Hydrosilanes (2.39 MB)

Gas Phase Studies of the Negative Ion Chemistry of Silicon (1.7 MB)

Iodotrimethylsilane (2.3 MB)

Organosilyl Peroxides (1.3 MB)

Oxidative Cleavage of the Silicon-Carbon Bond (1.90 MB)

The Chemistry of Cyanotrimethylsilane (4.5 MB)

Thermochemistry of Silanes, Halosilanes and Alkylsilanes (2 MB)

Trimethylsilyldiazomethane (681 Kb)

Hydrophobicity Hydrophilicity and Silanes.pdf (1,440 Kb)

Applied Technology

Factors contributing to the stability of alkoxysilanes in aqueous solutions (1,868 Kb)

Cyclic azasilanes: volatile coupling agents for nanotechnology (1,834 Kb)

Silane Blocking Agents (107 Kb)

Tailoring Surfaces with Silanes (1,842 Kb)

Applying a Silane Coupling Agent (17 Kb)

Infrared Analysis of Organosilicon Compounds: Spectra-Structure Correlations (233 Kb)

One-Part Silicone Sealants (756 Kb)

Spin-on-glass thin films prepared from a novel polysilsesquioxane ... (2,060 Kb)

High Density Silicon Dioxide Coatings by UV and Thermal Processing (1,517 Kb)

Look What You Can Make out of Silicones (3,101 Kb)

METAL CHEMISTRY

Introduction and Review Articles

Germanium vs. Silicon: A Brief Description (155 Kb)

Introduction to Organotin Chemistry (396 Kb)

Metal Alkoxides and Diketonates (174 Kb)

Double Metal Alkoxides / Heterometallic Alkoxides (184 Kb)

Applied Chemistry and Physics

Low Temperature Inorganic Chemical Vapor Deposition of Ti-Si-N Diffusion Barrier Liners for Gigascale Copper Interconnect Applications (662 Kb)

Low-temperature chemical vapor deposition of tantalum nitride ... (2,320 Kb)

Effects of Processing Parameters in the CVD of Co from Cobalt Tricarbonyl Nitrosyl (1.01 Mb)

Interlayer Mediated Epitaxy of Cobalt Silicide on Silicon (100) from Low Temp CVD of Cobalt (1.98 Mb)

High Density Silicon Dioxide Coatings by UV and Thermal Processing (1.48 Mb)

Synthesizing Low-k CVD Materials for Fab Use (2.36 Mb)

Tantalum diffusion barrier grown by inorganic plasma-promoted chemical vapor deposition: Performance in copper metallization (750 Kb)

Commercial Applications of Sol-Gel-Derived Hybrid Materials (783 Kb)

Barry C. Arkles - Publications

1. Theberge, J., Arkles, B., Cloud, P., Environmental, Thermal and Flammability Resistance of Glass Fortified Thermoplastics for Business Machine, Appliance and Tool Housings, 26th Soc. Plas. Ind. Composites Inst. Proc., 3-A, 22pp, 1971.

2. Theberge, J., Arkles, B., Cloud, P., Thermal and Environmental Resistance of Glass Reinforced Thermoplastics, Machine Design, 43, 1971.

3. Theberge, J., Arkles, B., Cloud, P., Glass Reinforced Thermoplastics, Machine Design, 43, 58, 1971.

4. Theberge, J., Arkles, B., Cloud, P., Low Cost Glass-Fortified Thermoplastic Resins for Automotive Applications, 27th Soc. Plas. Ind. Composites Inst. Proc., 14-C, 12pp, 1972.

5. Arkles, B., Solid Fluorocarbon Lubricants, Nat’l. Lubric. Grease Inst. (NLGI) Spokesman, 35(11), 390-8, 1972.

6. Theberge, J., Arkles, B., Chemical and Hydrolysis Resistance of Glass Fortified Thermoplastics, Materials Protection and Performance, 11(4), 25, 1972.

7. Arkles, B., Bonnet, R., Depolymerization of Polytetrafluoroethylene, Germ. Off. DE 2204141, Aug. 17, 1972.

8. Arkles, B., Recycling Polytetrafluoroethylene, ACS Org.Coat. Plas. Chem., 13(2), 812, 1972.

9. Arkles, B., Glass Fiber Stengthened Thermoplastics, Germ. Off., DE 2223022, Dec., 1972.

10. Theberge, J., Arkles, B., Cloud, P., Goodhue, R., Gear and Bearing Design with Lubricated and Reinforced Thermoplastics, 28th Soc. Plas. Ind. Composites Inst. Proc. (RPC Inst.), 5-E, 18pp, 1973.

11. Theberge, J., Arkles, B., Low Friction and Wear Thermoplastic Composites, ACS Org. Coat. Plas. Chem., 33(2), 188-94, 1973.

12. Theberge, J., Arkles, B., Cloud, P., How To Get High Accuracy Plastic Gears, Machine Design, 45, 140, 1973.

13. Arkles, B., Fluorocarbon Powder Coatings, The Australian Paint Journal, Sept. 1973.

14. Arkles, B., Glass-Reinforced Thermoplastics with Metallocene Coupling Agents, US Pat. 3,760,131, Oct. 1973.

15. Arkles, B., Pulberi De Acoperire Fluorocarburi Pseudolichide, Matiale Plastice (Roumania), 10(8), 450, 1973.

16. Arkles, B., Fluoropolymer Coatings, Vinyls and Polymers (Japan), Dec. 1973.

17. Theberge, J., Arkles, B., Goodhue, R. New Self-Lubricating Plastics, Machine Design, 45, 56, 1973.

18. Arkles, B., Theberge, J., Migratory Internal Lubrication of Thermoplastic Resins, Lubric. Eng., 29(12), 552-5, 1973.

19. Arkles, B., Recycling Polytetrafluoroethylene, in "Polymers and Ecological Problems" ed. J. Guillet, Plenum, p121, 1973.

20. Theberge, J., Arkles, B., Robinson, R., Carbon Fiber Reinforced Thermoplastics, 29th Soc. Plas. Ind. Composites Inst. Proc., 20D, 1974.

21. Theberge, J., Arkles, B., Robinson, R., Carbon Fibers Add Muscle to Plastics, Machine Design, 46(3), 102, 1974.

22. Arkles, B., Fluoplaster for Pulverbelaggning, Plastics World (Sweden), Feb., 1974.

23. Christian, J. B., Arkles, B., Poly(tetrafluoroethylene) and Fluorinated Ethylene-propylene Grease Lubricants, Lubric. Eng., 30(3), 136-43, 1974.

24. Arkles, B., Fluoropolymer Solid Lubricants, ACS Org. Coat. Plas. Chem., 34, 326-33, 1974.

25. Theberge, J., Arkles, B., Wear Characteristics of Carbon Fiber Reinforced Thermoplastics, Lubric. Eng., 30(12), 585-9, 1974.

26. Arkles, B., Poly(fluorocarbons) for Powder Coating, Kunststoffe, 64(7), 341-2, 1974.

27. Arkles, B., Bonnet, R., Super-heated Steam Depolymerization of Polytetrafluoroethylene, U.S. Pat. 3,832,41, Sept., 1974.

28. Theberge, J., Arkles, B., How Plastics Wear Against Plastics, Machine Design, 46, 1974.

29. Theberge, J., Arkles, B., Wear Characteristics of Carbon Fiber Reinforced Thermoplastics, Machine Design, 46, 1974.

30. Arkles, B., Gerakaris, S., Goodhue, R., Wear Characteristics of Fluoropolymer Composites in Advances in Polymer Friction and Wear" ed. L. H. Lee, Plenum, 663-688, 1974.

31. Arkles, B., Peterson, W., Fluoropolymer Solid Lubricants in "Advances in Polymer Friction and Wear" ed. L.H. Lee, Plenum, 453-467, 1974.

32. Theberge, J., Arkles, B., Cloud, P., Gerakaris, S., Elevated Temperature Performance of Thermoplastic Composites, 30th Soc. Plas. Ind. Composites Inst. Proc., 17-E, 16pp, 1975.

33. Theberge, J., Arkles, B., Cloud, P., Comparing High Temperature Plastics, Machine Design, 47(3), 73, 1975.

34. Theberge, J., Arkles, B., Cloud., P., Choosing Plastics for Chemical Resistance, Machine Design, 47(4), 103, 1975.

35. Theberge, J., Arkles, B., Cloud, P., How Time and Heat Affect the Properties of Plastics, Machine Design, 47(7), 79, 1975.

36. Arkles, B., Ewan, E., Nouvelle Poudres Pour Revetements A Haute Performances, Chimie-Actualities, (5), 40, 1975.

37. Arkles, B., Gerakaris, S., Apply a Function with Powder Coatings, Machine Design, 47(6), 103, 1975.

38. Arkles, B., Theberge, J., Robinson, R., Carbon Fibers Produced Specifically for Discontinuous Reinforcement of Thermoplastics, ACS Org. Coat. Plas. Chem., 36, 10, 1975.

39. Arkles, B., Gerakaris, S., Ewan, E., High Performanvce Functional Powder Coatings, Product Finishing, 40(1), 74-83, 1975.

40. Arkles, B., Theberge, J., Cloud, P., Long Term Properties of Thermoplastic Composites, Soc. Plas. Eng., RETECH, 164, Oct. 1975.

41. Theberge, J., Arkles, B., Robinson, R., Carbon Fiober Reinforced Thermoplastics, Soc. Adv. Mat. Proc. Eng. J., 20(11), 72, 1975.

42. Arkles, B., Brinigar, W., Respiratory Behavior of Rat Liver Mitochondria Immobilized on Alkylsilylated Supports, J. Biol. Chem., 250(22), 8856, 1976.

43. Arkles, B. Theberge, J., Carreno, C., Designing with Fiber Reinforced and Internally Lubricated Thermoplastic Elastomers, 32nd Soc. Plas. Ind. Composites Inst. Proc., 13-E, 1976.

44. Arkles, B., Theberge, J., Stronger Thermopastic Elastomers, Machine Design, 48(3), 113, 1976.

45. Arkles, B., Brinigar, W. S., Worthy, W., Immobilized Organelles Aid Cell Chemistry, Chem. Eng. News. 54(2), 17, Feb 9, 1976.

46. Theberge, J., Arkles, B., Robinson, R., Carbon Fiber Reinforced Thermoplastics, Ind. Eng. Chem. Prod. Res. Dev. 15(2), 100, 1976.

47. Arkles, B. Schireson, M. J., The Molecular Weight of PTFE Wear Debris, Wear, 39, 177, 1976.

48. Theberge, J. E., Cloud, P. J., Arkles, B., Predicting Wear in Reinforced Internally Lubricated Thermoplastics, Plastics World, 34(10), 46, 1976.

49. Arkles, B., Tailoring Inorganic Surfaces with Organosilanes, Am. Inst. Chem. Eng. Proc., 69, Dec. 1976.

50. Arkles, B., Theberge, J., Schireson, M., Wear Behavior of Thermoplastic Polymer Filled Fluorocarbon Composites, Compressed Air, (12), 1976.

51. Peterson, W., Arkles, B., Washburne, S., Reaction of Trimethylsilyl Azide with Bridged Bicylcic Olefins, J. Organomet, Chem., 121, 285, 1976,

52. Arkles, B. C., Respiratory Properties Of Rat Liver Mitochondria, Dissertation Abstracts B 1976 No. 99,11,977.

53. Arkles, B., Theberge, J., Schireson, M., Wear Behavior of Thermoplastic Polymer Filled Fluorocarbon Composites, Lubrication Engineering, 33(1), 33, 1977.

54. Theberge, J., Arkles, B., Knabb, D., Magnetic Molding Compounds, 32nd Soc. Plas. Ind Composites Inst. Proc., 32, 14-G, 1977.

55. Theberge, J., Arkles, B., Knabb, D., Molded Plastic Magnets, Machine Design, 49(2), 1977.

56. Arkles, B., Tailoring Surfaces with Silanes, CHEMTECH, 7(12), 766, 1977.

57. Arkles, B., Brinigar, W.S., Bound, Active Cellular Organelles and Method of Making Same, U.S. Pat. 4,078,971, March 14, 1978.

58. Arkles, B., Barbecuing - A Scientific Technological Effort, CHEMTECH, 8(8), IBC, 1978.

59. Arkles, B., Gerakaris, S., Fluorinated Ethylene-Propylene Copolymer Powders Having Improved Adhesion to Substrates, U.S. Pat. 4,110,186, Aug. 29, 1978.

60. Arkles, B., Peterson, W., The Effect of Silanes on Size-Free Glass Fibers in Thermoplastic Composites, Org. Coat. Plas. Chem, 40, 538, 1979.

61. Arkles, B., Peterson, W., New High Temperature Coupling Agents, 35th Soc. Plas. Ind. Composites Inst. Proc., 35, 20-A, 1980.

62. Arkles, B., Silanes and Silicones in Semiconductors and Microelectronics, SEMICON WEST Proc., 1980.

63. Arkles, B., Brinigar, W., Miller, A., Whole Cell and Cell Organelle Immobilization on Silica Substrates, in "Silylated Surfaces" (D. Leyden, W. Collins eds.) Gordon & Breach, New York, p.363, 1980.

64. Arkles, B., Peterson, W., High-Heat Silane Coupling Agents, Modern Plastics, 57(11), 69, 1980.

65. Arkles, B., New Generation Silicones for Medical Devices, Med. Dev. Diag. Ind. 3(4), 31, 1981.

66. Arkles, B. C., Peterson Jr., W. R., Method for the Production of Organic Polysilanes, U.S. Pat. 4,276, 424, June 30, 1981.

67. Arkles, B., Peterson, W. R., King, K., A New Class of Immobilizeable Phase Transfer Catalysts: The Silacrowns, in "Chemically Modified Surfaces in Catalysis and Electrocatalysis" (J. S. Miller ed.) Am. Chem. Soc., p. 281, 1982.

68. Peterson Jr., W. R., Arkles, B., C., Ethylene Bridged Amine Functional Silanes and Composites Using the Same, U.S. Pat. 4,336,395, June 22, 1982.

69. Arkles, B., Peterson, W., Silicon Compounds (Silanes), Kirk-Othmer Encyclopedia of Chemical Technology, 20, 887, 1982.

70. Arkles, B., Silicon Compounds (Ethers and Esters), Kirk-Othmer Encyclopedia of Chemical Technology, 20, 912, 1982.

71. Arkles, B., Silacrown Ethers, Method of Making Same, and Use as Phase Transfer Catalysts, U.S. Pat. 4,362,884, Dec. 7, 1982.

72. Arkles, B., Redinger, P. Silicones in Biomedical Devices in "Biocompatible Polymers, Metals and Composites" (M. Szycher ed.) Technomic, Lancaster, p749, 1983.

73. Arkles, B., Anderson, R., King, K., Silacrowns: Phase Transfer Catalysts, Organometallics, 2, 454, 1983.

74. Arkles, B., A Reactive Processing Method for IPN Thermoplastics, Poly. Mat. Sci & Engg., 49, 6, 1983.

75. Arkles, B., Look What You Can Make Out of Silicones (Biomedical Applications of Silicones), CHEMTECH, 13, 542, 1983.

76. Arkles, B., IPN Modified Silicone Thermoplastics, Med. Dev. Diag. Ind., 5, 1983.

77. Arkles, B., Carreno, C., Silicone IPN Modified Thermoplastics, Soc. Plas. Eng. 42nd ANTEC Proc., 486, 1984.

78. Arkles, B., High Performance and Thermoplastic Silicones for Biomedical Applications, Soc. Plas. Eng. 42nd ANTEC Proc., 1080, 1984.

79. Arkles, B., [2-(p-t-Butylphenyl)ethyl]silanes and Method of Making the Same, U.S. Pat. 4,469,881, Sep. 4, 1984.

80. Arkles, B., Carreno, C., Filler-Free Models for the Role of Organofunctional Silanes in Composites. Poly. Mat. Sci, Engg., 50, 440, 1984.

81. Arkles, B., Mixtures of Polyacrylate Resins and Siloxane-Carbonate Copolymers, U.S. Pat. 4,478,981, Oct. 23, 1984.

82. Pannell, K. H., LaNeave, C. K., Rico, E., Arkles, B., Concerning the Relative Non-toxicity of Silacrown Ionophores, Pharm. Biochem. Behav., 21, Supp. 1, 77, 1984.

83. Arkles, B., Peterson, W. R., Rokowski, J., Mixed Alkoxyaminosilanes, Methods of Making Same and Vulcanizing Silicones Prepared Therefrom. U.S. Pat. 4,491,669, Jan. 1, 1985.

84. Arkles, B., Curable Silicone Compositions and Methods of Making Same, U.S. Pat. 4,500,688, Feb. 19, 1985.

85. Arkles, B. What are IPN’s?, Plastics Technology, 31(8), 1985.

86. Arkles, B., C. Mixtures of Polyacrylate Resins and Siloxane-Styrene Copolymers, U.S. Pat. 4,500,139 Oct. 9, 1985.

87. Arkles, B., Silicon Nitride from Organosilazane Cyclic and Linear Prepolymers, J. Electrochem. Soc. 133, 233, 1986.

88. Arkles, B., Lydzinski, D., Brinigar, W., Chao, T., Siliconization: Blood - Surface Interaction in "Silanes, Surfaces and Interfaces" (D. Leyden ed.) Gordon & Breach, New York, 1986.

89. Arkles, B. C., Hamon, B. N., Method of Preparing Hexamethylcyclotrisilazane, U.S. Pat. 4,577,039, March 18, 1986.

90. Arkles, B. C., Mixtures of Polyacrylate Resins and Siloxane - Styrene Copolymers, Can. Pat. 1,204, 541 May 13, 1986.

91. Arkles, B. C., N-Methylhydridosilazanes, Polymers Thereof, Methods of making same and silicon nitrides produced therefrom, U.S. Pat. 4,595,775, June 17, 1986.

92. Arkles, B. C., Polysilane-Siloxane Oligomers and Copolymers and Methods of Making the Same, U.S. Pat. 4,626,583, Dec. 2, 1986.

93. Arkles, B., Steinmetz, J., Hogan, J., Polymeric Silanes: An Evolution in Coupling Agents, 42nd Soc. Plastics Ind. Composites Inst. Proc., 42, 21-C, 1987

94. Arkles, B. C., Pseudointerpenetrating Polymer Networks, U.K. Pat. 2,138,436 B, Feb. 25, 1987.

95. Arkles, B. C., Masse aus einem Silicon un einem thermoplastichen Polymer sowie Verfahren zu deren Herstellung, D.E. 3,314,355 C2, April 30, 1987.

96. Pannell, K. H., Rico, E., LaNeave, C., Rahimian, K., Amaya, A., Arkles, B., Silacrown Ionophores, J. Membrane Sci., 32, 83, 1987.

97. Arkles, B., Steinmetz, J., Hogan, J., Polymeric Silane Coupling Agents Enhance Strength of Composites, Modern Plastics, 64(4), 138, 1987.

98. Arkles, B. C., Methods of Using Silacrown Ethers as Catalysts, U.S. Pat. 4,699,991, Oct. 13, 1987.

99. Arkles, B. C., Brinigar, W. S., Method of Siliconization of Surfaces with Lower Alkyl Silanes, U.S. Pat. 4,711,820, Dec. 8, 1987.

100. Arkles, B. Curable Silicone Semi-Interpenetrating Polymer Networks and Methods of Making Same, U.S. Pat. 4,714,739, Dec. 22, 1987.

101. Arkles, B., Vogelaar, G., Better Way To Pick Silicone Fluid, Machine Design, 60(20), 81, 1988

102. Arkles, B. Curable Silicone Containing Compositions and Methods of Making Same, U.S. Pat. RE 33,070, Sep. 26, 1989

103. Arkles, B., Crosby, J., Polysiloxane - Thermoplastic Interpenetrating Polymer Networks, in "Silicon Based Polymer Science: A Comprehensive Resource" ed. J. Zeigler, G. Fearon, American Chemical Society, 1990.

104. Arkles, B. Chromogenic and Fluorogenic Silanes And Using The Same, U.S. Pat. 4,918,200, April 17, 1990

105. Arkles, B. Polysilane-Siloxane Oligomers and Copolymers and Methods of Making the Same, Japanese Pat. 1,562,810, June 12, 1990

106. Arkles, B., Smith, R., Secondary Cross-Linked Semi-Interpenetrating Polymer Networks And Methods of Making Same, U.S. Pat. 4,970,263, Nov. 13, 1990.

107. Arkles, B., King, K. Silakronether, Verfahren zu ihrer Herstellung und ihre Herstellung und ihre Verwendung, German Patent 32 43 048, Dec. 4, 1990.

108. Arkles, B., Hamon, B., Method of Preparing Hexamethylcyclotrisilazane, European Pat. 0,208,831, Jan., 16, 1991

109. Arkles, B., Steinmetz, J., Zazyczny, J., Zolotnitsky, M., Stable, Water-Borne Silane Coupling Agents, 46th Soc. Plas. Ind. Composites Inst. Proc., 46, 2-D, 7pp, 1991.

110. Arkles, B., Steinmetz, J., Zazyczny, J., Mehta, P., Factors Contributing to the Stability of Alkoxysilanes in Aqueous Solution, J. Adhesion Sci. & Technol., 6, 193, 1992; also included in "Silanes and Other Coupling Agents" ed. K. Mittal, VSP, 1992, p 91.

111. Faltermeier, F., Eisenbraun, E., Liu, J., Dettelbacher, C., Toscano, P., Arkles., B., Kaloyeros, A., MOCVD of Tungsten for Multilayer Interconnects, in "Advanced Metallization for VLSI Applications 1992" eds. T. Cale, F. Pintchovski, Mat. Res. Soc. 1993

112. Arkles, B., Larsen, G. Preparation of Sterically-Hindered Silanes, U.S. Pat. US Pat. 5,296,624, March 22, 1994.

113. Arkles, B., Future Directions in Silicon Chemistry, Main Group Chemistry News, 2(2), 4 1994.

114. Arkles, B. Hydroxymethyltriethoxysilane and Hydrolysis and Condensation Products Derived Therefrom, U.S. Pat. 5,371,262, December 6, 1994

115. Arkles, B. Hydroxymethyltriethoxysilane und deren Herstellungs- und Verwendungsverfahtren, Ger. Off. DE 4407 437 A1 15-9-94.

116. Goldberg, C., Eisenbraun, E., Komarov, S., Faltermeier, C., Chen, X., Jones, M., Avanova, A., Flordalice, R., Pintchovski, F., Arkles, B., Hepp, A., Kaloyeros, A., Low Temperature In-Situ Chemical Vapor Deposition of Ti/TiN Ultrathin Bilayers for ULSI Barrier Applications in "Advanced Metallization for ULSI Applications 1994" eds. R. Blumenthal, G. Janssen, Mat. Res. Soc. 1995

117. Steinmetz, J., Arkles, B., Preparation of Stable Water-borne Silane Compositions, Eur. Pat. Appl. EP 675128 A1, 1995.

118. Arkles, B., Kaloyeros, A. Conformal Titanium Based Films and Method for Their Preparation, US. Pat Application. 08/322,020, 1994, PCT Int. Appl. WO 9612048 A2 960425, 1996.

119. Arkles, B., Grignard Reagents and Silanes in "Handbook of Grignard Reagents" G. Silverman and P. Rakita eds, Marcel-Dekker, p.667, 1996.

120. Faltermeier, C., Goldberg, C., Jones, M., Upham, A., Manger, D., Peterson, G., Lau, J., Kaloyeros, A., Arkles, B., Paranjpe, A., Barrier Properties of Titanium Nitride Films Grown by Low Temperature Chemical Vapor Deposition from Titanium Tetraiodide," J. Electrochemical Society, 144, 1002, 1997.

121. Arkles, B., Berry, D., Figge, L., Composto, R. Chiou, T., Colazo, H., Wallace, W., Staged Development of Silicon Dioxide Films, Journal of Sol-Gel Science and Technology, 8, 465, 1997

122. Arkles, B., Silicon Compounds (Silanes), Kirk-Othmer Encyclopedia of Chemical Technology, 22, 38, 1997, Wiley.

123. Arkles, B., Silicon Compounds (Ethers and Esters), Kirk-Othmer Encyclopedia of Chemical Technology, 22, 69,1997, Wiley.

124. Faltermeier, C., Goldberg, C., Jones, M., Upham, A., Kerr, A., Ivanova, A., Peterson, G., Kaloyeros, A., Arkles, B., The Effects of Processing Parameters in the Low-Temperature Chemical Vapor Deposition of Titanium Nitride from Tetraiodotitanium," J. Electrochemical Society, 145, 676, 1998.

125. Lin, L., Endisch, D., Chen, X., Kaloyeros, A., Arkles, B., Silicon Nitride Films Deposited by Atmospheric Pressure Chemical Vapor Deposition, MRS Proc., 495, 107, 1998.

126. Kumta, P., Hepp, A., Beach, D., Arkles, B., Sullivan, J., editors "Chemical Aspects of Electronic Ceramics Processing", MRS, 1998.

127. Chen, X., Frisch, H., Kaloyeros, A., Arkles, B., Low Temperature Plasma-Promoted Chemical Vapor Deposition of Tantalum from Tantalum Bromide for Copper Metallization, J. Vac. Sci. Technol., B 16(5), 2887, 1998.

128. Arkles, B., Berry, D. Figge, L., Method of Using Siloxane Polymers, US Pat. 5,853,808, Dec. 29, 1998

129. Arkles, B. Branched Higher Alkylsilanes, US Pat. 5,874,603, Feb. 23, 1999.

130. Chen, X., Frisch, H., Kaloyeros, A., Arkles, B., Low Temperature Plasma-Promoted Chemical Vapor Deposition of Tantalum Nitride from Tantalum Bromide for Copper Metallization, J. Vac. Sci. Technol., B 17(1), 182, 1999.

131. Kelsey, J., Goldberg, C., Nuesca, G., Peterson, G., Kaloyeros, A., Arkles, B., Low Temperature Metal-Organic Chemical Vapor Deposition of Tungsten Nitride as Diffusion Barrier for Copper Metallization, J. Vac. Sci. Technol., B 17(3), 1101, 1999.

132. Chen, X., Peterson, G., Goldberg, C., Nuesca, G., Frisch, H., Kaloyeros, A., Arkles, B., Sullivan, J., Low-Temperature Chemical Vapor Deposistion of Tantalum Nitride from Tantalum Pentabromide for Integrated Circuity Copper Metallization Applications, J. Mater. Res., 14(5), 2043, 1999.

133. Arkles, B., Kaloyeros, A. Tantalum and tantalum-based films and methods for making same, US Pat. 5,919,531, July 6, 1999.

134. Pan, Q., Gonzalez, B., Composto, R., Wallace, W., Arkles, B., Figge, L., Berry, D Spin-on-glass thin films prepared from a novel polysilsesquioxane by thermal and ultraviolet-irradiation methods, Thin Solid Films, 345, 244, 1999

135. Arkles, B.C., Kaloyeros, A. E., Silicon nitrogen-based films and method of making the same precursors and method of making the same. PCT Int’l Appl. WO 99 27,154, June 10, 1999.

136. Arkles, B., Kaloyeros, A. Silicon based films formed from iodosilane precursors and method of making the same, PCT Int’l WO 99 28,529, June 10, 1999

137. Ivanova, A., Nuesca, G., Chen, X., Goldberg, C., Kaloyeros, A., Arkles, B., Sullivan, J., The Effects of processing parameters in the chemical vapor deposition of cobalt from cobalt tricarbonyl nitrosyl, J. Electrochem. Soc., 146(6), 2139, 1999.

138. Arkles, B., Kaloyeros, A. Silicon nitrogen-based films and method of making the same, US Pat. 5,968,611 October 19, 1999

139. Arkles, B. Hybrid Polymers in the Marketplace, CHEMTECH, 29(12), 7, 1999.

140. Arkles, B., Commercial Hybrid Organic-Inorganic Polymers in "Organosilicon Chemistry IV" eds. Auner, N, Weiss, J., p.592-612, Wiley-VCH, 2000.

141. Kaloyeros, A., Arkles, B., Method for the Chemical Vapor Deposition of Copper-Based Films, US Pat. 6,037,001 March 14, 2000.

142. Kaloyeros, A., Arkles, B., Method for the Chemical Vapor Deposition of Copper-Based Films and Copper Source Precursors for the same, US Pat. 6,066,196 May 23, 2000.

143. Nau, D., Gan, K., Arkles, B., Sheng, G., Zhou, H., Recovery or organic solutes from aqueous solutions, US Pat. 6,0741,410 (PCT Int’l WO 2000029088), June 6, 2000.

144. Kaloyeros, A. E., Arkles, B.C., Methods for the chemical vapor deposition and preparation of conformal titanium-based films, US Pat., 6,090,709, July 18, 2000.

145. Arkles, B., Kaloyeros, A., Chemical Vapor Deposition of Tungsten Nitride, PCT Int’l WO 2000047404, 2000.

146. Ezbiansky, K., Arkles, B., Composto, R., Berry, D., b-Acetoxyethyl Silsesquioxanes: Chloride-Free Precursors for SiO2 Films via Staged Hydrolysis, MRS Proc., 606, 251, 2000

147. Eisenbraun, E., Upham, A., Dash, R., Zeng, W., Hoefnagels, J., Lane, S., Anjum, D., Dovidenko, K., Kaloyeros, A., Arkles, B., Sullivan, J., Low temperature inorganic chemical vapor deposition of Ti-Si-N diffusion barriers for gigascale copper interconnect applications, J. Vac. Sci. Technol. B 18(4), 2011, 2000

148. Kaloyeros, A., Arkles, B., Tantalum and tantalum based films formed using Fluorine-containing Source Precursors and methods for making the same" US Pat. 6,139,922, Oct. 31, 2000

149. Laxman, R., Hendricks, N., Arkles, B., Tabler, T., Synthesizing Low-k Materials for Fab Use, Semiconductor International, Nov., 2000

150. Kaloyeros, A., Chen, X., Lane, S., Frisch, H., Arkles, B., Tantalum diffusion barrier grown by inorganic plasma-promoted chemical vapor deposition: Performance in copper metallization, J. Mater. Res., 15(12), 2000.

151. Londergan, A., Nuesca, G., Goldberg, C., Peterson, G. Kaloyeros, A., Arkles, B., Sullivan, J., Interlayer Mediated Epitaxy of Cobalt Silicide on Silicon (100) from Low Temperature Chemical Vapor Deposition of Cobalt: Formation Mechanisms and Associated Properties J. Electrochem. Soc., 148, C21, 2001

152. Ezbiansky, K., Berry, D., Composto, R., Arkles, B. Fluoride Catalyzed Conversion of b-acetoxethylsilsesquioxane: chloride free precursor for silica films, Polymer Preprints, 42(12), 2001

153. Arkles, B. Commercial Applications of Sol-Gel-Derived Hybrid Materials, MRS Bulletin, 26(5), 402, 2001

154. Steinmetz, J., Arkles, B., Method for the Preparation of Stable Water-borne Silane Compositions, EP 01201939.4-2110, July 18, 2001.

155. Arkles, B., Pan, Y., Larson, G., Production of alkoxysilanes with alkali metal hydrides in chloride-free process, PCT INt’l WO 2001058908, 2001

156. Arkles, B., Kaloyeros, A., Methods for chemical vapor deposition of titanium-silicon-nitrogen films, PCT Int’l Appl. WO 2001079584, 2001

157. Kaloyeros, A., Londergan, A., Arkles, B., Method of interlayer mediated epitaxy of cobalt silicide from low temperature chemical vapor deposition of cobalt. US Pat. 6,346,477, Feb. 12, 2002

1. G. A. Arbuckle, N. M. Buecheler, C. Clark,, A. Wille, "A Quartz Crystal Microbalance Study of the Vapor Phase Doping of Polyacetylene", Synth. Met. 1994, 63, 35.

2. J. Holub, A. E. Wille, B. Stíbr, P. J. Carroll, L. G. Sneddon, "A Simple High-Yield Sulfur Insertion Reaction: Synthesis and Structural Characterizations of New 11-Vertex aracno-Dithiaborane Clusters", Inorg. Chem.1994, 33, 4920.

3. J. W. Bausch, R. C. Rizzo, L. G. Sneddon, A. E. Wille, R. E. Williams, "An ab-inito/GLO/NMR Investigation of nido-C₄B₇H₁₁ Configurations: Structural Assignment of the Three Known Isomers and Reconfirmation of Empirical Carbon Placement Patterns" Inorg. Chem., 1996, 35, 131.

4. A. E. Wille, K. Su, P. J. Carroll, L. G. Sneddon, "New Synthetic Routes to Azacarbaborane Clusters: Nitrile Insertion Reactions of nido-5,6-C₂B₈H₁₁- and nido-B₁₀H₁₃-" J. Am. Chem. Soc., 1996, 118, 6407.

5. A. E. Wille, P. J. Carroll, L. G. Sneddon, "Synthesis of Mono-B-alkylcyclotriborazane: Structural Characterization of 2-(PhC₂H₄)B₃N₃H₁₁" Inorg. Chem., 1996, 35, 5101.

6. A. E. Wille, J. Plesek, B. Stíbr, J. Holub, P. J. Carroll, L. G. Sneddon, "An Improved Synthesis of arachno-4-CB₈H₁₄ and Crysallographic and Ab initio/IGLO/NMR Investigations of the Solid State and Solution Structures of the arachno-4-CB₈H₁₃- Anion" Inorg. Chem., 1996, 35, 5342.

1. W. K. Musker and G. L. Larson, "Intramolecular Interactions Involving Group IV Elements. Spectral Properties of 1-(Trimethylsilyl)-2-Propanone", J. Organomet. Chem., 6, 627 (1966).

2. W. K. Musker and G. L. Larson, "Synthesis of the Cis and Trans Isomers of 2-Trimethylsilyl-cyclohexanol", Tetrahedron Lett., 3481 (1968).

3. W. K. Musker and G. L. Larson, "The Stereochemistry of the Beta Elimination Reactions in Organosilanes", J. Am. Chem. Soc., 91, 514 (1969).

4. D. S. Matteson and G. L. Larson, "Boron-Tin and Boron-Lead Tetrametallomethanes", J. Am. Chem. Soc., 91, 6541 (1969).

5. D. S. Matteson, R. B. Castle and G. L. Larson, "Tetrakis(acetoxymercury)methanes", J. Am. Chem. Soc., 92, 231 (1970).

6. R. T. Gray, J. Diekman, G. L. Larson, W. K. Musker and C. Djerassi, "Electron-Impact Induced Fragmentations and Rearrangements of Alkoxycyclohexanol Trimethylsilyl Ethers and Alkoxycyclohexyl Trimethylsilanes", Org. Mass Spec., 3, 973 (1970).

7. D. S. Matteson and G. L. Larson, "Tin and Lead Derivatives of tetrakis(dimethoxyboryl)-methane", J. Organomet. Chem., 57, 225 (1973).

8. G. L. Larson and A. Hernandez, "The Reaction of Trimethylsilyl Enol Ethers with Diols", J. Org. Chem., 38, 3935 (1973).

9. G. L. Larson and A. Hernandez, 'The Reaction of Trimethylsilyl Enol Ethers with 2-Mercapto-ethanol", Synthetic Commun., 4, 61 (1974).

10. G. L. Larson, D. Hernandez and A. Hernandez, "The Hydroboration of Trimethylsilyl Enol Ethers", J. Organomet. Chem., 76, 9 (1974).

11. G. L. Larson and Y. V. Fernandez, "The Mechanism of the Thermal Rearrangement of Beta Ketosilanes", J. Organomet. Chem., 86, 193 (1975).

12. G. L. Larson and O. Rosario, "A Synthesis of a, b-Unsaturated Esters via Ethyl Lithio-trimethylsilylacetate", Rev. Latinoamer. Quim., 6, 16 (1975).

13. G. L. Larson, E. Hernandez, C. Alonso and I. Nieves, "A Synthesis of Olefins via Hydroboration of Cyclic Trimethylsilyl Enol Ethers", Tetrahedron Lett., 4005 (1975).

14. G. L. Larson and A. Hernandez, "The Stereochemistry of the b-Elimination of b-Trimethyl-siloxy Organoboranes", J. Organomet. Chem., 102, 123 (1975).

15. G. L. Larson, V. Nemeth and H. Valente, "A Convenient Synthesis of Arylsilanes from Chloro-benzenes", Syn. React. Inorg. Metalorg. Chem., 6, 21 (1976).

16. M. de Jesus, O. Rosario and G. L. Larson, "The Hydroboration-Oxidation of the Isomeric Trimethylsilylcyclohexenes and the Isomeric Trimethylsilylcyclopentenes", J. Organomet. Chem., 132, 301 (1977).

17. O. Rosario, A. Oliva and G. L. Larson, "A Synthesis of a-Hydroxysilanes", J. Organomet. Chem., 146, C8 (1978).

18. J. D. White and G. L. Larson, "The Reduction of Organic Substrates with Ytterbium-Ammonia Solution", J. Org. Chem., 43, 4555 (1978).

19. A. Oliva and G. L. Larson, "The Reaction of Chloromethylsilanes with Lithium Diisopropyl-amide", Rev. Latinoamer. Quim., 10, 54 (1979).

20. G. L. Larson and O. Rosario, "The Formation and Alkylation of (Tri-methylsilyl), (Phenyl-dimethylsilyl)- and (Diphenylmethylsilyl)- Dichloromethyllithium. Preparation of a,a-Dichloroalkylsilanes and ((Z)-1-Chloro-1-alkenyl)silanes", J. Organomet. Chem., 168, 13 (1979).

21. G. L. Larson and L. Fuentes, "A Reductive 1,2-Transposition of Acyclic Ketones", Synthetic Commun., 9, 841 (1979).

22. R. S. -C. Tsai, G. L. Larson and A. Oliva, "A Mass Spectral Study of 1-(Aryldimethylsilyl)-2-Propanones and Their Isomeric 2-(Aryl- dimethylsilyl)-1-Propenes", Org. Mass Spec., 14, 364 (1979).

23. G. L. Larson, R. Arguelles, O. Rosario and S. Sandoval, "The Preparation of a- Hydroxy-organosilanes from Alpha Boryl Organosilyl Intermediates", J. Organomet. Chem., 198, 15 (1980).

24. J. A. Prieto and G. L. Larson, "Preparation of Trans-2-Acyl Cyclopentanols and Cyclo-hexanols", Synthetic Commun., 10, 675 (1980).

25. O. Rosario, S. Sandoval and G. L. Larson, "The Reaction of (Phenyldimethylsilyl)dichloro-methyllithium with Organoboranes. A Synthesis of a-Hydroxyorganosilanes and Ketones", Synthetic Commun., 10, 813 (1980).

26. A. Oliva and G. L. Larson, "Sintesis y Propiedades Espectrales de 1-(Arildimetilsilil)-2 propanonas y 2-(Arildimetilsiloxi)propenos", Rev. Latinoamer. Quim., 11, 143 (1980).

27. G. L. Larson and L. del Valle, "The Reaction of Silanes with Chloroform Under Phase Transfer Conditions: An Unfortunate, Convenient Preparation of Disiloxanes" Syn. React. Inorg. Metal. Org. Chem., 11, 173 (1981).

28. G. L. Larson and L. M. Fuentes, "The C-Silylation of Lithium Ester Enolates", J. Am. Chem. Soc., 103, 2418 (1981).

29. G. L. Larson, J. A. Prieto and A. Hernandez, "Thermodynamic and Kinetic Control in the Reaction of Carboethoxymethylenetriphenylphosphorane and Ethyl Lithiotrimethylsilyl-acetate with 2-(tert-Butyldimethylsilyl-oxy)cycloalkanones", Tetrahedron Lett., 22, 1575 (1981).

30. G. L. Larson, M. Ortiz, M. Rodriguez de Roca, "The Reaction of Tri-methylsilyl Esters with Metal Hydride Reducing Agents. Protection of Carboxylic Acids as Their Trimethylsilyl Esters During Hydroboration", Synthetic. Commun., 11, 583 (1981).

31. L. del Valle, S. Sandoval and G. L. Larson, "The Preparation of a, a-Dichloromethylsilanes Under Phase Transfer Conditions", J. Organomet. Chem., 215, C45 (1981).

32. L. M. Fuentes and G. L. Larson, "A Facile Synthesis of 4-oxo Carboxylic Acids From g-Butyrolactone", Tetrahedron Lett., 23, 271 (1982).

33. G. L. Larson and D. Hernandez, "Facile Synthesis of Symmetrical 1,1-Disubstituted Ethylenes", Tetrahedron Lett., 23, 1035, (1982).

34. G. L. Larson and M. Ortiz, "The Reaction of Sulfonyl Azides With Organoboranes", Synthetic Commun., 12, 43 (1982).

35. G. L. Larson and C. Cadiz, "Attempted Generation of Halocarbenes: Protodesilylation of Dihalomethylsilanes", J. Organometal. Chem. 232, 113-116 (1982).

36. G. L. Larson and J. A. Prieto, "Entries into Prostanoid Models via the Hydroboration of Enol Silyl Ethers", Tetrahedron, 39, 855 (1983).

37. G. L. Larson, S. Sandoval, F. Cartledge and F. R. Fronczek, "a-Haloethylsilanes Optically Active at Carbon and at Silicon: Synthesis and Absolute Configuration", Organometallics, 2, 810 (1983).

38. G. L. Larson, J. Organometallic Chem. Libr., 13, 387 J. Oliver and R. B. King, Eds., Elsevier Scientific Publishing Co., New York 1983. (Book-Chapter)

39. G. L. Larson, F. Quiroz and J. Suarez, "Studies on the Stereoselectivity of the Preparation of a, b-Unsaturated Esters from a-Lithio a-Silyl Esters", Synthetic Commun., 13, 833 (1983).

40. G. L. Larson and V. Cruz de Maldonado, "A Silicon Mediated Conversion of Esters to Terminal Olefins and Specifically Deuterated Olefins", Synthetic Commun., 13, 1163 (1983).

41. G. L. Larson, I. Montes de Lopez-Cepero and L. E. Torres, "An Efficient Synthesis of Beta Ketosilanes" Tetrahedron Lett., 25, 1673 (1984).

42. G. L. Larson, C. Fernandez de Kaifer, R. Seda, L. E. Torres and J. R. Ramirez, "A Stereo-selective, Two-Step Preparation of a-Alkyl, a, b-Unsaturated Esters", J. Org. Chem., 49, 3385 (1984).

43. G. L. Larson and D. Hernandez, "The Synthesis of Tri- and Tetra-Substituted Olefins From Alpha Silyl Esters", J. Org. Chem., 49, 4285 (1984).

44. G. L. Larson, J. Organometallic Chem. Libr., 14, 267 J. Oliver and R. B. King Eds., Elsevier Scientific Publishing Co., New York, (Book-Chapter).

45. G. L. Larson, "a-Silyl Carbonyl Compounds: Synthesis and Characterization", "Silicon Compounds: Register and Review", Petrarch Systems, Inc. Bristol, PA. 22 (1984) Review.

46. G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for 1982", J. Organometal. Chem., 274, 29 (1984) (Book-Chapter).

47. G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for 1983", J. Organometal. Chem. Libr., 17, pp 1-162 J. Oliver Ed., Elsevier Publishing Co., New York, (1985) (Book-Chapter).

48. G. L. Larson and E. Torres, "Asymmetric Induction by Chiral Silicon Groups", J. Organometal. Chem., 293, 19, (1985).

49. G. L. Larson and R. Klesse, "An Improved Synthesis of the Ethylene Acetal of 3-Iodopropanal and The Ethylene Ketal of 4-Iodo-2-butanone", J. Org. Chem., 50, 3627 (1985).

50. G. L. Larson and R. M. Betancourt de Perez, "A Two-Step Preparation of a-Ylidene Gamma Lactones From g-Lactones: A Synthesis of Racemic Ancepsenolide", J. Org. Chem., 50, 5257 (1985).

51. G. L. Larson, D. Hernandez, I. Montes de Lopez-Cepero and L. E. Torres, "The Reaction of Alpha (Diphenylmethylsilyl) Esters with Grignard Reagents: A Synthesis of b-Ketosilanes and Ketones. The Synthesis of the Douglas Tussock Fir Moth Pheromone", J. Org. Chem., 50, 5260 (1985).

52. G. L. Larson, A. Santiago and I. Montes de Lopez-Cepero, "A Synthesis of 2,2-Ethylenedioxy 5-Ketones", Synthetic Commun., 16, 705 (1986).

53. G. L. Larson, A. Santiago and I. Montes de Lopez-Cepero, "A Synthesis of 2,2-Ethylenedioxy 6-Ketones", Synthetic Commun. 16, 697 (1986).

54. G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for the year 1984, J. Organomet. Chem. (Book-Chapter), 313, 141 (1986).

55. R. M. Betancourt de Perez, G. L. Larson, C. L. Barnes and M. J. Heeg, "A Synthesis of 4-Oxo Carboxylic Acids, 4-Oxo Aldehydes, and 1,4-Diketones from g-Lactones", J. Org. Chem., 51, 2039 (1986).

56. G. L. Larson, E. Torres, C. Burgos Morales, G. J. McGarvey, "The Preparation and Reactions of (E) a-Lithio-a-(Methyldiphenylsilyl) Alkenes", Organometallics, 5, 2274 (1986).

57. L. E. Torres and G. L. Larson, "The Palladium (II)Acetate-Mediated 6-Endo-Trig Cyclization of 1,1-Dialkyl-2-Silyloxy-1,5-Dienes", Tetrahedron Lett., 27, 2223 (1986).

58. V. Cruz de Maldonado and G. L. Larson, "The (Methyldiphenylsilylation) of Carboxylic Acid Dianions", Synthetic Commun., 16, 1347 (1986).

59. G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for the year 1985", J. Organometal. Chem. 337, 195-430 (1987).

60. Y. -S. Lee, L. del Valle, G. L. Larson, "A Ready Preparation of 2-(2-Iodoethyl)-1,3-dioxane: A Facile three-Carbon Extension of Grignard Reagents", Synthetic Commun., 17, 385 (1987).

61. M. A. de Jesus, J. A. Prieto, L. del Valle, G. L. Larson, "Trichloromethyl-anion Chemistry from Trimethylsilyl Trichloroacetate", Synthetic Commun., 17, 1047 (1987).

62. G. L. Larson, R. Klesse and F.K. Cartledge, "Thermal Rearrangement of (S,S)-1-Naphthyl-phenylmethyl(1-chloroethyl)silane and (S)-(1-Chloro-ethyl)phenyldimethylsilane", Organometallics, 6, 2250, 1987.

63. G. L. Larson, I. Montes de Lopez-Cepero and L. Rodriguez, "a-Diphenyl-methylsilylation of Ester Enolates: 2-Methyl-2-Undecene from Ethyl Decanoate", Organic Synthesis, 67, 125 (1988).

64. G. L. Larson, V. Cruz de Maldonado, L.M. Fuentes and L.E. Torres, "The Methyldiphenyl-silylation of Ester and Lactone Enolates", J. Org. Chem., 53, 633 (1988).

65. E. Torres, G. L. Larson and G. J. McGarvey, "An Asymmetric Hydrogen Equivalent: Use of the 1-Napthylphenylmethylsilyl Group in the Synthesis of Optically Active Allyl Alcohols and 1-Phenyl-1,2-Butadiene", Tetrahedron Lett., 29, 1355 (1988).

66. J. A. Prieto, J. Suarez and G. L. Larson, "The Regioselectivity of Deprotonation of Unsymmetrical Ketones with Lithium Tert-Butyltrilakylsilyl Amides", Synthetic Commun., 18, 253 (1988).

67. G. L. Larson, "An Introduction to Organosilicon Chemistry", Silicon Compounds, Register and Review, Petrarch Systems, 1987.

68. W. R. Peterson, R. Anderson, G. L. Larson, "Silane Blocking Agents", Silicon Compounds, Register and Review, Petrarch Systems, 1987.

69. G. L. Larson (with B. Arkles and R. Anderson) editor of "Silicon Compounds, Register and Review", Petrarch Systems, 1987.

70. G. L. Larson, "Organosilanes in Organic Synthesis" VIIIth International Symposium on Organosilicon Chemistry, St. Louis, MO 1987.

71. J. A. Prieto, G. L. Larson, R. Berrios, A. Santiago, "A Silicon Facilitated Preparation of 1,3 Dienes", Synthetic Commun., 18, 1385 (1988).

72. G. L. Larson, C. L. Barnes, S. B. Sandoval, "Trans -1,2,5-triphenyl-1-silacyclopentane", Acta Cryst., C44, 1147 (1988).

73. C. L. Barnes, G. L. Larson, Y. -S. Lee, "Trans 1,1,2,5-tetraphenyl-1-silacyclopentane", Acta Cryst., C44, 1148 (1988).

74. C. L. Barnes, G. L. Larson., A. Santiago, J. Rios Steiner, "Ethyl 3-(2-Methyl-1,3-dioxolan-2-yl)-2-(methyldiphenylsilyl)propionate", Acta Cryst. C44, 1323 (1988).

75. G. L. Larson, J. A. Prieto, E. Ortiz, "The Preparation and Chemistry of (R)-(1-Naphthyl)-phenylmethylsilylmethyllithium: Stereochemistry at Silicon in the Elimination of b-Hydroxysilanes", Tetrahedron, 44, 3781 (1988).

76. J. A. Prieto, G. L. Larson, R. Berrios, "A Regio- and Stereoselective Synthesis of Enol (Methyldiphenylsilyl) Ethers", Tetrahedron Lett., 30, 283 (1989).

77. G. L. Larson, "Recent Synthetic Applications of Organosilanes" in The Chemistry of Organic Silicon Compounds S. Patai and Z. Rappoport, eds. John Wiley & Sons, Ltd. 1989, Chapter 11 pp 764-808.

78. G. L. Larson, J. A. Prieto, L. del Valle, "The Reaction of a,a-Dichloro-benzyltrimethylsilane with Some Aldehydes and Ketones", Synth. Commun., 19, 1405 (1989).

79. J. A. Prieto, G. L. Larson, P. Gonzalez, "The Stereochemistry of the Reaction of a-Silyl Lithium Reagents with Cyclic Tert-Butyldimethylsilyl Acyloins", Synthetic Commun. 19, 2773 (1989).

80. G. L. Larson, J. A. Prieto, P. Gonzalez, "A Synthesis of Fused Butenolides", Synthetic Commun., 19, 2779 (1989).

81. G. L. Larson, "Silicon The Silicon-Carbon Bond: Annual Survey for the Year 1986, J. Organometal. Chem., 360, 39 (1989).

82. G. L. Larson, "Silicon-The Silicon-Carbon Bond: Annual Survey for the Year 1987", J. Organometal. Chem., 374, 1 (1989).

83. G. L. Larson, J. A. Soderquist, M. Rivera Claudio, "Preparation of b-Silyl-a,b-Unsaturated Esters and 3-Silyl Allyl Alcohols", Synthetic Commun., 20, 1095-1104 (1990).

84. G. L. Larson, "a-Silyl Carbonyl Compounds" Pure and Applied Chemistry, Pure and Applied Chemistry, 62, 2021 (1990).

85. F. R. Fronczek, G. L. Larson and J. Suarez, "Racemic tert-Butyl-(1-Naphthylphenylmethyl-silyl) Acetate", Acta Cryst., C46, 2480 (1990).

86. G. L. Larson, "Silicon The Silicon-Carbon Bond: Annual Survey for the Year 1988, J. Organometal. Chem., 1991.

87. G. L. Larson, "Trimethylsilyl Iodide", Silicon Compounds, Register and Review, Hüls America, Inc., 1991.

88. G. L. Larson, "Trimethylsilylnitrile", Silicon Compounds, Register and Review, Hüls America, Inc., 1991.

89. G. L. Larson, "Trimethylsilyldiazomethane", Silicon Compounds, Register and Review, Hüls America, Inc., 1991.

90. G. L. Larson, "Silicon The Silicon-Carbon Bond: Annual Survey for the Year 1989, J. Organometal. Chem., 1991.

91. G. L. Larson, Editor "Advances in Silicon Chemistry" Volume 1, 1992.

92. G. L. Larson, F. C. Cartledge, R. Nunez, R. J. Unwalla, R. Klesse, L. Del Valle, "The Preparation of (a,a-Dichlorobenzyl)silanes and (a-Halobenzyl)silanes" Organometallics, 11, 859 (1992).

93. J. A. Prieto, M. T. Pallares, G. L. Larson, "Preparation and Reactions of Ethyl 1-(Diphenyl-methylsilyl)cyclopropane Carboxylate", Synlett., 199 (1993).

94. T. J. Delord, F. R. Fronczek, R. M. Betancourt de Perez, G. L. Larson, "Structure of an a-(Methyldiphenylsilyl)-g-lactone", Acta Cryst., C49, 1799 (1993).

95. G. L. Larson, "Trimethylsilyl-t-butylamine", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

96. G. L. Larson, "Methyldiphenylchlorosilane", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

97. G. L. Larson, "Trimethylsilylacetone", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

98. G. L. Larson, "N,N-Dimethyl-2-(trimethylsilyl)acetamide", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

99. G. L. Larson, "Ethyl a-(Methyldiphenylsilyl)propionate", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

100. G. L. Larson, "Ethyl a-(Methyldiphenylsilyl)acetate", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

101. G. L. Larson, R. R. Chawla, C. S. Subramaniam, T. V. John, "A Commercially Viable Synthesis of Cyanotrimethylsilane", Org. Proc. Res. Dev., 1, 90 (1997).

102. G. L Larson, "The Chemistry of a-Silyl Carbonyl Compounds" in Advances in Silicon Chemistry, Vol 3, G. L. Larson ed. JAI Press, Greenwich, CT. USA.

103. A. Ricci, G. C. Seconi, R. Curci, G. L. Larson, "Organyosilyl Peroxides", in Advances in Silicon Chemistry, Vol 3, G. L. Larson, ed. JAI Press, Greenwich, CT USA.

104. R. Chawla, G. L. Larson, "Preparation of 1,1,3,3-Tetraissopropyl-1,3-dichlorodisiloxane and Triispropylchlorosilane", Synthetic Commun. 29, 3499, 1999.

Gerald L. Larson - Patents

1. G. L. Larson, B. Arkles, "Preparation of Sterically-Hindered Silanes", US 5,296,624 (1992).

2. G. L. Larson, T. V. John, R. R. Chawla, C. S. Subramaniam, "Preparation of Trialkylsilyl Nitriles", US 5,258,534 (1992).

3. G. Bernhardt, M. Haas, H. Kragl, G. L. Larson, "Pyridinium Salts Containing Alkoxysilyl Groups", US 5,235, 051 (1994).

4. G. Bernhardt, M. Haas, H. Kragl, G. L. Larson, "Pyridinium Salts Containing Alkoxysilyl Groups", US 5,371, 216 (1994).

5. S. E. Wilson, G. L. Larson, P. N. Hazin, "Olefinpolymerisationskatalysator", EP 0,611,779 (1994).

6. C. S. Subramaniam, G. L. Larson, "Synthesis of Silyl Cyanohydrins", US 5,594,156, (1997).

7. G. L. Larson, J. Zazyczny, L. E. Linder, "Preparation of Waterborne Silane/Titanium Chelates Composition", US 5,796,117, (1998).

8. T. V. John, G. L. Larson, C. S. Subramaniam, "Process for Producing Cyanoformate Esters", US 5,852,207, (Dec. 22, 1998).

9. G. L. Larson, R. Chawla, "Preparation of Acyloxysilanes", US 5,902,892, (May 11, 1999).

10. G. L. Larson, R. Chawla, "Preparation of Alkyl(amino)dialkoxysilane", US 6,114,558, (September 5, 2000).

11. B. Arkles, Y. Pan, G. Larson, "Chloride-Free Process for the Production of Alkylsilanes suitable for Microelectronic Applications", US 2002/0002299 A1

12. B. C. Arkles, G. L. Larson, Y. Pan, "Trialkylsilanes for Use in Chromatographic Applications, Substrates Including Such Compounds and Methods of Producing Same", US 6,410,770, (June 25, 2002).

Youlin Pan - Publications

1. Reactions of 1,2-Dihalodisilanes with Alkali Metal Amides: Formation and Structure of a Tetrahydrodibenzo[b,f][1,5]-disilocine. M. Weidenbruch, Y. Pan, K. Peters and H. G. von Schnering, Chem. Ber., 122, 1989, 885.

2. A Bicyclic Disilane from the Reaction of 1,2-Dichlorotetramesityldislane with Lithium tert-Butyl Amide. M. Weidenbruch, Y. Pan, K. Peters and H. G. von Schnering, Chem. Ber., 122, 1989, 1483.

3. A Spirocyclic Silane from a 2,2-Dimesityldisilanes. M. Weidenbruch, Y. Pan, K. Peters and H. G. von Schnering, Chem. Ber., 123, 1990,795.

4. Disilane und ein Disilen mit unsymmetrischer Substitution an den Silicumatomen. M. Weidenbruch, A. Pellmann, Y. Pan, S. Pohl and W. Saak, J. Organomet. Chem., 450, 1993, 67.

5. Stable Bissilyl Palladium Complexes: Synthesis, Structure, and Bissilyation of Acetylenes. Y. Pan, J. T. Mague and M. J. Fink, Organometallics, 11, 1992, 3495.

6. Synthesis, Structure, and Unusual Reactivity of d¹⁰-d¹⁰ Palladium(0) Dimer. Y. Pan, J. T. Mague and M. J. Fink, J. Am. Chem. Soc., 115, 1993, 3842.

7. Why Si=Si Double Bond Compounds are So Difficult to Synthesize. Y. Pan and Y. Wang, Daxue Huaxue, 6, 1991, 46

8. The Synthesis and Properties of Si=Si Double Bond Compounds. Y. Pan and Y. Wang, Daxue Huaxue, 8, 1993, 67.

9. Novel Reactivity of d¹⁰-d¹⁰ Palladium Complex. R. Landtiser, Y. Pan and M. J. Fink, Phosphorus, Sulfur, and Silicon and the Related Elements, 93-94, 1993, 393.

10. Phenylated Group 13/15 Compounds: Convenient Precursors To Phase Pure Gallium Arsenide And Gallium Phosphide. Y. Pan and P. Boudjouk, Main Group Chemistry, 1, 1995, 61.

11. A Novel Lithocenophane Derivative of a Trisgermole Dianion:{Li⁺•.[(2,3,4,5-tetraethylgermole)₂]-(2,3,4,5-tetraethylgermole)}•{[Li^+](TMEDA)(THF)}. J. H. Hong, Y. Pan and P. Boudjouk, Angew. Chem., 35, 1996, 186.

12. Surprising Reaction of Non-Nucleophilic Bases with 1-Hydrosiloles: Addition and Not Deprotonation. Y. Pan, J. H. Hong, S. B. Choi and P. Boudjouk, Organometallics, 36, 1997, 1445.

13. Mechanistic Studies of the Reaction of Hydrosiloles with Nucleophiles. Crystal Structures of the Enantiomers of 1-Methyl-2-(dimethylsilyl)-2,3,4,5-tetraphenyl-1-silacyclo-3-pentene and 1-(Bis(trimethylsilyl)amino)-5-methyl-2,3,4,5-tetraphenyl-1-silacyclo-3-pentene. S. B. Choi, P. Boudjouk and Y. Pan, Organometallics, 18, 1999, 3813.

Ben Fieselmann - Publications

1. Optimization of CIS Heterojunction Window Layers and Scale-up for Large Area Sub-Module Application, Proceedings of the 23d IEEE Symposium, 581-585 (1993) by L. Russell, B. Fieselmann, and R. R. Arya.

2. CIS Solar Cells By Elemental Sputtering, Proceeding of the 22d IEEE Symposium, 903-906 (1991) by R. R. Arya, T. Lommasson, B. Fieselmann, L. Russell, L. Carr, and A. Catalano.

3. Optical and Phototransport Properties of a-Si C:H Produced by Disilylmethane and Hydrogen Diluted Methane, Proceeding of the 22d IEEE Symposium, 1231-1235 (1991) by Y-M Li, B. Fieselmann and A. Catalano.

4. Review of Progress on a-Si Alloy Solar Cell Research, Solar Cells, 27, 25-37(1989) by A. Catalano, R.R. Arya, M. Bennett, L. Yang, J. Morris, B. Goldstein, B. Fieselmann, J. Newton, and S. Wiedeman.

5. Preparation and Evaluation of p-Type Materials for a-Si Solar Cells Using DC Plasma Discharge Deposition of Trimethylboron, Material Research Society Proceedings 149, 441-445 (1989) by B. F. Fieselmann and B. Goldstein.

6. Solar Cells: Present Status and Future Prospects, Journal of Non-Crystalline Solids 115, 14-20 (1989) by A. Catalano, R. Arya, B. Fieselmann, B. Goldstein, J. Newton, S. Wiedemann, M. Bennet, and D. Carlson.

7. Improved Synthetic Route to Potassium Silyl Using Crown Ethers, Potassium, and Silane, and its Use to Prepare Methylsilane and Disilylmethane, Journal of Organometallic Chemistry 363, 1-5 (1989) by B. F. Fieselmann and C. R. Dickson.

8. Amorphous Silicon Solar Cells with Ethylene-based p-Layers, Applied Physics Letters 54, 1537-1539 (1989) by S. Wiedemann, M. Smoot, and B. F. Fieselmann.

9. Purity Considerations for Amorphous Silicon Thin Films, Journal of Crystal Growth 89, 49-61 (1988) by C. R. Dickson, B. F. Fieselmann, and R. S. Oswald.

10. Doping and Alloying Amorphous Silicon Using Silyl Commpounds, Proceeding of the 19th IEEE Symposium (1987), 1510-1511 by B. F. Fieselmann and C. R. Dickson.

11. Electronic and Structure of Bis(Ti(II) Bipyridyl Compounds, Journal of the American Chemical Society 101, 3425(1979) by B. Fieselmann, G. Stucky, D. Lichtenberger, A. McPherson and G. McPherson.

12. Binuclear Ti(III) Compounds with Pyrazole and Biimidzole, Inorganic Chemistry 17, 2078 (1978) by B. Fieselmann, D Hendrickson, and G. Stucky.

13. Binuclear Ti(III) Pyrazole Compounds, Inorganic Chemistry 17, 2074 (1978) by B. Fieselmann and G. Stucky

14. Trinuclear and Dinuclear Ti(III) Compounds with Cyanuric Acid and Uracil, Inorganic Chemistry 17, 1841 (1978) by B. Fieselmann, D. Hendrickson, and G. Stucky.

15. Crystal Structure of Cp2TiCl, Journal of Organometallic Chemistry 137, 43 (1977) by B. Fieselmann and G. Stucky.

16. Improved Bubbler, Journal of Chemical Education 54, 652 (1977) by B. Fieselmann and G. Stucky

17. Calculations of Chemical Bond Energies, An. Acc. Brasil 44 217 (1972) by R. Ferreira and B. Fieselmann

Ben Fieselmann - Patents

5,496,583 For improved fluoride dopant sources for preparing conductive oxide coated films

5,358,755 For preparation and deposition of organosilicon compounds

4,777,023 For use of crown ethers to prepare silyl salts as synthetic intermediates leading to organosilanes

4,341,741 For recovery of precious metal catalyst from carbonylation reaction residues